Complete recipeSource: Main
Route 1: Solvothermal
2 · 2.3. Synthesis of Cu3(HBC)2
Metal precursorsCu(NO3)2.3H2O, 9.6 mg (0.04 mmol)
Linker precursorsHBC, 7.0 mg (0.01 mmol); HBC itself was synthesised according to literature [29,33]
Solvents2 mL water for Cu(NO3)2.3H2O; 0.5 mL N,N-dimethylacetamide (DMAc) for HBC
Atmospherenot specified
Temperature85
Time72
Work-upcool to room temperature; collect by centrifugation; wash successively with water, DMF, and THF
Activationdried under vacuum
Scalability contextNo scale-up experiment reported; small-batch synthesis used milligram precursor quantities.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cu(NO3)2.3H2O | 9.6 mg (0.04 mmol) | 2 · 2.3. Synthesis of Cu3(HBC)2 |
| Linker | HBC | 7.0 mg (0.01 mmol) | 2 · 2.3. Synthesis of Cu3(HBC)2 |
| Solvent | water | 2 mL | 2 · 2.3. Synthesis of Cu3(HBC)2 |
| Solvent | N,N-dimethylacetamide (DMAc) | 0.5 mL | 2 · 2.3. Synthesis of Cu3(HBC)2 |