Metal precursorsCuCl2, 0.6 g
Linker precursors4-nitrophthalonitrile, 1.9 g
SolventsHCl solution; NaOH solution; DMF; Milli-Q water
Additivesurea, ammonium molybdate; Na2S.9H2O reductant
Atmospherenot reported
Temperature160; 90; 60; 70
Time5; 1; 2; 6
Oxidant / reductantNa2S.9H2O used to reduce Cu(II) tetranitrophthalocyanine to CuTAPc
Work-upInitial product stirred in 1 M HCl and NaOH at 90 deg C, cooled, filtered, washed with Milli-Q water; reduction product introduced into water and centrifuged with water until neutral.
ActivationDried in vacuum oven at 60 deg C for 8 h after first stage; final solid dried at 70 deg C for 6 h.
Scalability contextPrecursor synthesis on gram scale for first solid-state stage; no scale-up discussion.
Show 9 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|
| Linker | 4-nitrophthalonitrile | 1.9 g | SI text · S1.2 Synthesis of CuTAPc |
| Metal Source | CuCl2 | 0.6 g | SI text · S1.2 Synthesis of CuTAPc |
| Additive | urea | 4.8 g | SI text · S1.2 Synthesis of CuTAPc |
| Additive | ammonium molybdate | 100 mg | SI text · S1.2 Synthesis of CuTAPc |
| Acid | HCl | 100 mL · 1 M | SI text · S1.2 Synthesis of CuTAPc |
| Base | NaOH | 100 mL · 1 M | SI text · S1.2 Synthesis of CuTAPc |
| Other | Cu(II) 4,4,4,4-tetranitrophthalocyanine | 0.75 mg | SI text · S1.2 Synthesis of CuTAPc |
| Reductant | Na2S.9H2O | 2.9 g | SI text · S1.2 Synthesis of CuTAPc |
| Solvent | DMF | 30 mL | SI text · S1.2 Synthesis of CuTAPc |