Wang H., Zhu C., Wu M. et al. · Journal of Materials Science · 2021 · 2517-2527
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Ni-MOF//AC ASC devices show practical energy-storage potential, with 30.7 Wh kg-1 at 225 W kg-1 and high cycling retention.
Caveat: Device values depend on activated carbon negative electrode and cell design, not only the pristine MOF.
9 · Electrochemical characterization · Figure 5 · Linked to 3 structured results
Ni-MOF is a promising supercapacitor electrode material, giving 318 F g-1 at 1 A g-1 and stable cycling.
Caveat: Performance is in a composite electrode with acetylene black/PTFE binder rather than a binder-free pristine framework conductivity test.
6-7 · Electrochemical characterization · Figure 4 · Linked to 2 structured results
The paper is categorised as conductive-MOF evidence through electrochemical/EIS conductivity claims, but it does not report a direct four-probe or two-probe bulk electrical conductivity value.
Caveat: Direct transport measurements were not found in the main text or SI text.
6-9 · Electrochemical characterization · Figures 4c and 5f · Linked to 2 structured results
Commercial activated carbon served as the negative electrode component in the Ni-MOF//AC ASC and had its own SI electrochemical control data.
Caveat: AC control values are estimated from SI Fig. S3 axes; the SI caption does not give a full AC electrode preparation recipe.
Fig. S3 caption/text · Figure S3 · Linked to 3 structured results
The double-ligand conjugated framework and nickel centres improved redox capability and electronic conductivity.
Caveat: No direct bulk electrical conductivity measurement is reported; evidence is from electrochemical performance, EIS resistance and qualitative discussion.
1-2 · Abstract / Introduction · Linked to 3 structured results
The hollow, porous Ni-MOF structure promotes electrolyte storage/diffusion and supports electrochemical performance.
Caveat: Morphology is directly observed, but the performance linkage is interpretive.
2,4 · Introduction / Structure and morphology · Figure 3 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| commercial activated carbon YEC-8A | activated carbon; exact composition not reported | unknown · DerivedCommercial activated carbon used as the ASC negative electrode and electrochemical control. | Fig. S3 caption/text · Figure S3 |
| double-ligand Ni-MOF | Product 1; empirical formula not stated in the extracted textbinuclear Ni2O(O2C)4 units with Ni2+ centres · H2L ligand from terephthaloyl chloride and (R/S)-phenylalanine methyl ester; 4,4'-bipyridine (Bpy) | 1D · PristineChiral orthorhombic P21212 one-dimensional MOF; 1D chains on the ab plane strengthened by Bpy coordination between adjacent Ni2O clusters. | 4 · Structure and morphology · Figure 1 |
| Ni-MOF//AC asymmetric supercapacitor | Ni-MOF positive electrode plus activated carbon negative electrodeNi nodes from Ni-MOF positive electrode · H2L and Bpy in Ni-MOF | 1D · CompositeAsymmetric supercapacitor assembled from Ni-MOF positive electrode and activated carbon negative electrode. | 7 · Electrochemical characterization · Figure 5 |
| Ni-MOF composite electrode film | Ni-MOF:acetylene black:PTFE = 7:2:1 on nickel foamNi nodes from Ni-MOF · H2L and Bpy in Ni-MOF | 1D · CompositeComposite working electrode made from Ni-MOF active material, conductive carbon and PTFE binder pressed onto nickel foam. | 3 · Electrochemical measurements |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| activated carbon control electroderesearch_0548__mat__mat_activated_carbon | Electrode · Composite Component · Derived Carbon | Commercial AC (YEC-8A) electrode/control used for electrochemical measurements and as ASC negative electrode component; detailed electrode recipe not separately reported in SI text. | Fig. S3 caption/text · Figure S3 |
| Ni-MOF//AC ASC deviceresearch_0548__mat__mat_ni_mof_ac_asc | Electrode · Composite Sample · Composite | Ni-MOF positive electrode with 2 mg active loading and activated carbon negative electrode with 1 mg loading; positive:negative mass ratio 2:1. | 7 · Electrochemical characterization · Figure 5 |
| Ni-MOF working electrode on nickel foamresearch_0548__mat__mat_ni_mof_electrode | Electrode · Composite Sample · Composite | Ni-MOF, acetylene black and PTFE mixed 7:2:1, dried at 60 deg C for 5 h, pressed onto nickel foam.nickel foam · about 0.1 mm film | 3 · Electrochemical measurements |
| Ni-MOF green powderresearch_0548__mat__mat_ni_mof | Powder · Target Sample · Pristine Framework | Green powder product after washing with ethanol and water and drying at 60 deg C for 12 h. | 3 · Synthesis of Ni-MOF |