Yu S., Zhao H., Wang Y. et al. · Applied Organometallic Chemistry · 2024 · e7658
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Mn-MOF-140 C is presented as a high-performance air-cathode catalyst for lithium-oxygen batteries with high capacity and 140 cycles.
Caveat: The electrode is a composite containing conductive Super-P and Nafion, so application performance is not a pristine-framework electrical transport measurement.
1 · Abstract · Linked to 7 structured results
FTIR and XPS are used to support successful coordination of Mn2+ with 2,4-PDCA in the Mn-MOF.
Caveat: No single-crystal structure or CIF is provided in the assigned documents.
5-6 · Results and discussion · Figure 2c-g · Linked to 5 structured results
The 140 C Mn-MOF sample is claimed to combine ordered layered orientation, defects, lower charge-transfer resistance, and higher ion diffusion, giving the best LOB performance.
Caveat: Direct electrical conductivity is claimed qualitatively but not measured quantitatively.
8 · Conclusions · Linked to 9 structured results
The authors propose that Mn-MOF air cathodes adsorb LiO2 and induce a film-like discharge product, preventing further oxidation to Li2O2 and improving cycling stability.
Caveat: Mechanistic evidence is mainly Raman peak assignment and schematic interpretation; no direct in situ structural measurement is reported.
8 · Results and discussion · Figure 4g,h · Linked to 3 structured results
N-element and metal-ion coordination in Mn-MOFs are claimed to improve material conductivity and ORR/OER reaction kinetics.
Caveat: No standalone electrical conductivity measurement is reported; conductivity improvement is inferred from coordination and electrochemical performance.
8 · Conclusions · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| manganese-based metal-organic framework (Mn-MOF) | not reportedMn2+ from manganese(II) acetate tetrahydrate · 2,4-pyridinedicarboxylic acid (2,4-PDCA) | 2D · Pristineordered layered/high-orientation Mn-MOF nanosheet material; 140 C sample described as uniformly oriented and defect-containing | 1 · Abstract |
| commercial MnO2 cathode control | MnO2Mn oxide · not applicable | unknown · Unknowncommercial non-MOF control used for LOB cycling comparison | 8 · Results and discussion · Figure S2 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Mn-MOF-120 C air cathoderesearch_0566__mat__mat_mn_mof | Electrode · Composite Sample · Composite | sprayed catalyst layer on PTFE-treated carbon paperhydrophobic carbon paper support/levelling layer | 3 · Electrode preparation |
| Mn-MOF-120 Cresearch_0566__mat__mat_mn_mof | Powder · Target Sample · Pristine Framework | solvothermal powder heated at 120 C for 24 h | 3 · Synthesis of Mn-MOF cathode catalytic materials |
| Mn-MOF-140 C air cathoderesearch_0566__mat__mat_mn_mof | Electrode · Composite Sample · Composite | sprayed catalyst layer on PTFE-treated carbon paperhydrophobic carbon paper support/levelling layer | 7 · Results and discussion · Figure 4 |
| Mn-MOF-140 Cresearch_0566__mat__mat_mn_mof | Nanosheet · Target Sample · Pristine Framework | solvothermal powder heated at 140 C for 24 h | 4 · Results and discussion · Figure 1c,g-i |
| Mn-MOF-160 C air cathoderesearch_0566__mat__mat_mn_mof | Electrode · Composite Sample · Composite | sprayed catalyst layer on PTFE-treated carbon paperhydrophobic carbon paper support/levelling layer | 7 · Results and discussion · Figure 4 |
| Mn-MOF-160 Cresearch_0566__mat__mat_mn_mof | Powder · Target Sample · Pristine Framework | solvothermal powder heated at 160 C for 24 h | 3 · Synthesis of Mn-MOF cathode catalytic materials |
| Mn-MOF-180 C air cathoderesearch_0566__mat__mat_mn_mof | Electrode · Composite Sample · Composite | sprayed catalyst layer on PTFE-treated carbon paperhydrophobic carbon paper support/levelling layer | 7 · Results and discussion · Figure 4 |
| Mn-MOF-180 Cresearch_0566__mat__mat_mn_mof | Powder · Target Sample · Pristine Framework | solvothermal powder heated at 180 C for 24 h | 5 · Results and discussion · Figure 2c |
| Mn-MOF-200 C air cathoderesearch_0566__mat__mat_mn_mof | Electrode · Composite Sample · Composite | sprayed catalyst layer on PTFE-treated carbon paperhydrophobic carbon paper support/levelling layer | 7 · Results and discussion · Figure 4 |
| Mn-MOF-200 Cresearch_0566__mat__mat_mn_mof | Powder · Target Sample · Pristine Framework | solvothermal powder heated at 200 C for 24 h | 5 · Results and discussion · Figure 2c |
| Mn-MOF temperature-series powdersresearch_0566__mat__mat_mn_mof | Powder · Target Sample · Pristine Framework | solvothermal powders prepared at 120, 140, 160, 180, and 200 C | 4 · Results and discussion · Figure 1 |
| commercial MnO2 air cathoderesearch_0566__mat__mat_mno2_control | Electrode · Pristine Control · Composite | commercial MnO2 cathode control; preparation not described in available textnot reported | 8 · Results and discussion · Figure S2 |