Spectroscopy — Ordered layered manganese-based metal–organic frameworks induce 2D growth of discharge products via LiO2 adsorbent for high performance lithium–oxygen batteries

4 measurement groups · 21 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Mn-MOF temperature-series powders · Powder

Varian 640 FT-IR spectrometer

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-C tensile vibration	1613 cm-1	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2c
=C-H tensile vibration	3050 cm-1 for 180 and 200 C samples	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2c
C-N tensile vibration	1664 cm-1	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2c
Mn-N bond vibration	1014 cm-1	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2c
Mn-O bond vibration	452 cm-1	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2c
O-H tensile vibration	2352 cm-1	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2c

Mn-MOF-140 C air cathode · Electrode

140 C Mn-MOF air cathode after different charge-discharge cycles

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li2O2 Raman peak absence	Li2O2 peak at 790 cm-1 not observed	—	—	Text Qualitative	8 · Results and discussion · Figure 4g
LiO2 Raman peak	1132 cm-1	—	—	Text Rounded Reported	8 · Results and discussion · Figure 4g

Mn-MOF temperature-series powders · Powder

Horiba Labram, room-temperature wavenumber range 50-3500 cm-1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
140 C Raman peak	1610 cm-1	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2b
140 C Raman peak	3087 cm-1	—	—	Text Rounded Reported	5 · Results and discussion · Figure 2b

Mn-MOF-140 C · Nanosheet

ThermoFisher Scientific K-Alpha; Mn 2p, N 1s, O 1s, C 1s spectra

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C 1s binding energy for C=C	284.49 eV	—	—	Text Exact Reported	6 · Results and discussion · Figure 2g
C 1s binding energy for C-N	288.07 eV	—	—	Text Exact Reported	6 · Results and discussion · Figure 2g
C 1s binding energy for C-C	285.35 eV	—	—	Text Exact Reported	6 · Results and discussion · Figure 2g
C 1s binding energy for O-C=O	291.05 eV	—	—	Text Exact Reported	6 · Results and discussion · Figure 2g
Mn 2p1/2 binding energy	653.41 eV	—	—	Text Exact Reported	5 · Results and discussion · Figure 2d
Mn 2p3/2 binding energy	641.77 eV	—	—	Text Exact Reported	5 · Results and discussion · Figure 2d
Mn satellite peak	645.77 eV	—	—	Text Exact Reported	5 · Results and discussion · Figure 2d
N 1s binding energy for N-Mn-O	399.79 eV	—	—	Text Exact Reported	5 · Results and discussion · Figure 2e
N 1s binding energy for N in PDCA	398.95 eV	—	—	Text Exact Reported	5 · Results and discussion · Figure 2e
O 1s binding energy for C-O in PDCA	532.73 eV	—	—	Text Exact Reported	5-6 · Results and discussion · Figure 2f
O 1s binding energy for Mn-O	531.17 eV	—	—	Text Exact Reported	5-6 · Results and discussion · Figure 2f