Electrical Transport — Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism

Measurement evidence

Electrical Transport

Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism · Tkachov R., Stepien L., Grafe R. et al. · Polymer Chemistry · 2018 · 4543-4555

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electrical conductivity versus pellet density

P1 poly[Kx(Ni-ett)] · Pellet

300 K compressed pellets pressed under different pressure.

Temperature
300
Atmosphere
ambient
Geometry
compressed pellet
Context
density-control measurement
Measurement source
4 · Thermoelectric properties · Table SA1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity_at_density_2.02352.35SI Table
Exact Reported
4 · Thermoelectric properties · Table SA1
conductivity_at_density_2.04442.69SI Table
Exact Reported
4 · Thermoelectric properties · Table SA1
conductivity_at_density_2.08642.95SI Table
Exact Reported
4 · Thermoelectric properties · Table SA1

Electrical conductivity versus pellet density

P3 poly[Ni-tto] · Pellet

300 K compressed pellets pressed under different pressure.

Temperature
300
Atmosphere
ambient
Geometry
compressed pellet
Context
density-control measurement
Measurement source
4 · Thermoelectric properties · Table SA2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity_at_density_2.010629.79SI Table
Exact Reported
4 · Thermoelectric properties · Table SA2
conductivity_at_density_2.027830.5SI Table
Exact Reported
4 · Thermoelectric properties · Table SA2
conductivity_at_density_2.106234.63SI Table
Exact Reported
4 · Thermoelectric properties · Table SA2

Ambient stability of conductivity

P1 poly[Kx(Ni-ett)] · Pellet

Conductivity monitored under ambient atmosphere over about one month.

Atmosphere
ambient atmosphere
Geometry
compressed pellet
Context
pristine control
Measurement source
5 · Thermoelectric properties · Fig. SA3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ambient_conductivity_decayconductivity of P1 drops 2 times over a few daysText
Approximate
5 · Polymerization III · Fig. SA3

Ambient stability of conductivity

P3 poly[Ni-tto] · Pellet

Conductivity monitored under ambient atmosphere over about one month.

Atmosphere
ambient atmosphere
Geometry
compressed pellet
Context
target pristine polymer
Measurement source
5 · Thermoelectric properties · Fig. SA3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ambient_conductivity_retentionP3 remains at almost the same level over one monthText
Qualitative
5 · Polymerization III · Fig. SA3