Electrochemistry Application — Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism

2 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

P1 poly[Kx(Ni-ett)] · Pellet

CH3CN, 0.1 M tetrabutylammonium hexafluorophosphate, N2, 50 mV s^-1, Fc/Fc+ referenced to 0.00 V.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
irreversible_ni_reduction_vs_vacuum	-3.5 eV	—	—	Text Approximate	8 · Cyclic voltammetry · Fig. 5
irreversible_ni_reduction_vs_fc	-1.59 V	—	—	Text Rounded Reported	8 · Cyclic voltammetry · Fig. 5
partial_ni_reduction_energy_max	-4.7 eV	—	—	Text Range	8 · Cyclic voltammetry · Fig. 5
partial_ni_reduction_energy_min	-5.0 eV	—	—	Text Range	8 · Cyclic voltammetry · Fig. 5

P3 poly[Ni-tto] · Pellet

CH3CN, 0.1 M tetrabutylammonium hexafluorophosphate, N2, 50 mV s^-1, Fc/Fc+ referenced to 0.00 V.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
quasi_reversible_redox_wave_vs_vacuum	-4.5 eV	—	—	Text Rounded Reported	7 · Cyclic voltammetry · Fig. 5
quasi_reversible_redox_wave_vs_fc	-0.59 V	—	—	Text Rounded Reported	7 · Cyclic voltammetry · Fig. 5
irreversible_sulphur_oxidation_centre	0.9 V	—	—	Text Rounded Reported	7 · Cyclic voltammetry · Fig. 5
cv_scan_rate	50 mV s^-1	—	—	Text Exact Reported	11 · Characterization techniques