cMOF Evidence Base
Electrical Transport — CH⋯Cl relevant discrepancy on structure, magnetic and electronic conductivity of two mixed-valence CuICuII coordination polymers

Measurement evidence

Electrical Transport

CH⋯Cl relevant discrepancy on structure, magnetic and electronic conductivity of two mixed-valence CuICuII coordination polymers · Shi L., Yang P., Huang G. et al. · Journal of Solid State Chemistry · 2011 · 1699-1706

2 measurement groups · 37 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

complex impedance spectroscopy fitted with ZView equivalent circuit

Impedance spectroscopy

Compound 1 powder/PVDF/Cu mesh impedance sample · Electrode

Frequency range 0.01-10 kHz; temperatures 315-335 K; compound/PVDF on copper mesh after vacuum sintering.

Temperature
315-335
Atmosphere
vacuum drying/sintering before measurement; measurement atmosphere not specified
Geometry
electrode/sample/electrode configuration; copper wire mesh area 2 cm2
Context
pristine framework powder embedded in PVDF/electrode composite for measurement
Measurement source
6-7 · 3.5 Electrical conductivity studies · Figs. 9-10; Table 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
compound 1 fitted CPE at 315 K1.00e-05——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted CPE at 320 K2.95e-05——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted CPE at 325 K2.64e-05——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted CPE at 330 K1.54e-04——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted CPE at 335 K2.88e-04——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R1 at 315 K500——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R1 at 320 K78.9——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R1 at 325 K79.8——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R1 at 330 K9.52——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R1 at 335 K7.46——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R2 at 315 K500——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R2 at 320 K463——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R2 at 325 K521——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R2 at 330 K42.9——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 fitted R2 at 335 K38.6——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 1 semiconductor behaviouractivated conduction mechanism like a semiconductor material——Text
Qualitative		6 · 3.5 Electrical conductivity studies · Fig. 9a

complex impedance spectroscopy fitted with ZView equivalent circuit

Impedance spectroscopy

Compound 2 powder/PVDF/Cu mesh impedance sample · Electrode

Frequency range 0.01-10 kHz; temperatures 315-335 K; compound/PVDF on copper mesh after vacuum sintering.

Temperature
315-335
Atmosphere
vacuum drying/sintering before measurement; measurement atmosphere not specified
Geometry
electrode/sample/electrode configuration; copper wire mesh area 2 cm2
Context
pristine framework powder embedded in PVDF/electrode composite for measurement
Measurement source
6-7 · 3.5 Electrical conductivity studies · Figs. 9-10; Table 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
compound 2 fitted CPE1 at 315 K2.22e-03——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE1 at 320 K2.34e-03——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE1 at 325 K5.79e-03——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE1 at 330 K6.69e-03——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE1 at 335 K7.52e-03——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE2 at 315 K2.16e-04——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE2 at 320 K1.87e-04——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE2 at 325 K1.76e-04——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE2 at 330 K8.50e-05——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted CPE2 at 335 K3.82e-05——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R1 at 315 K2.429——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R1 at 320 K2.021——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R1 at 325 K1.865——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R1 at 330 K1.844——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R1 at 335 K1.841——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R2 at 315 K27.75——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R2 at 320 K6.73——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R2 at 325 K5.26——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R2 at 330 K0.969——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 fitted R2 at 335 K0.834——Table
Exact Reported		7 · 3.5 Electrical conductivity studies · Table 4
compound 2 semiconductor behavioursemiconductor behaviour similar to compound 1, with lower resistance——Text
Qualitative		7 · 3.5 Electrical conductivity studies · Table 4