Synthesis · CH⋯Cl relevant discrepancy on structure, magnetic and electronic conductivity of two mixed-valence CuICuII coordination polymers

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

2 · 2.2 Synthesis

Metal precursorsCuCl2.2H2O (0.4 mmol, 0.0682 g)

Linker precursorsH2qdiol (0.6 mmol, 0.0973 g); bpy (0.3 mmol, 0.0469 g)

Solventsethanol (10 mL)

Additivesethanolic NaOH to adjust pH to 8

Atmospheresealed Teflon-lined stainless steel reactor; gas atmosphere not specified

Temperature140

Time72

Oxidant / reductantCu(II) partially reduced to Cu(I) under solvothermal conditions; no separate reductant specified

Work-upcooled at 3 C/h to 100 C and then 5 C/h to room temperature; crystals collected and washed with distilled water

Activationnone reported for isolated crystals

Scalability context23 mL Teflon-lined stainless steel reactor; isolated yield 0.0679 g.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CuCl2.2H2O	0.4 mmol, 0.0682 g	2 · 2.2 Synthesis
Linker	H2qdiol	0.6 mmol, 0.0973 g	2 · 2.2 Synthesis
Linker	bpy	0.3 mmol, 0.0469 g	2 · 2.2 Synthesis
Solvent	ethanol	10 ml	2 · 2.2 Synthesis
Base	ethanolic NaOH	to pH 8	2 · 2.2 Synthesis