Other — CH⋯Cl relevant discrepancy on structure, magnetic and electronic conductivity of two mixed-valence CuICuII coordination polymers

4 measurement groups · 15 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

As-isolated bulk crystals of compound 1 · Powder

Polycrystalline sample measured on Quantum Design MPMS-XL5 over 2-300 K; susceptibility per Cu(II) unit.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
compound 1 chiM T at 2 K	0.40 cm3 K mol-1	—	—	Text Exact Reported	4 · 3.4 Bulky purity and magnetic properties · Fig. 8a
compound 1 chiM T at room temperature	0.42 cm3 K mol-1	—	—	Text Exact Reported	4 · 3.4 Bulky purity and magnetic properties · Fig. 8a
compound 1 Curie constant	0.42 cm3 K mol-1	—	—	Text Exact Reported	4 · 3.4 Bulky purity and magnetic properties · Fig. 8a
compound 1 magnetic fit g	2.12	—	—	Text Exact Reported	6 · 3.4 Bulky purity and magnetic properties · Fig. 8a
compound 1 magnetic fit zj prime	-2.1 x 10-3 cm-1	—	—	Text Exact Reported	6 · 3.4 Bulky purity and magnetic properties · Fig. 8a
compound 1 Weiss constant	-2.2 x 10-3 K	—	—	Text Exact Reported	4 · 3.4 Bulky purity and magnetic properties · Fig. 8a

As-isolated bulk crystals of compound 1 · Powder

Yield based on Cu; CHN elemental analysis; IR measured with KBr pellets over 4000-400 cm-1.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
absence of carbonyl IR band for 1	no strong peaks around 1700 cm-1	—	—	Text Qualitative	2 · 3.1 Synthesis · Fig. S1
isolated yield of compound 1	0.0679 g (71% based on Cu)	—	—	Text Exact Reported	2 · 2.2 Synthesis

As-isolated bulk crystals of compound 2 · Powder

Polycrystalline sample measured on Quantum Design MPMS-XL5 over 2-300 K; susceptibility per Cu(II) unit.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
compound 2 chiM T at 20 K	0.38 cm3 K mol-1	—	—	Text Exact Reported	4 · 3.4 Bulky purity and magnetic properties · Fig. 8b
compound 2 chiM T at 2 K	0.48 cm3 K mol-1	—	—	Text Exact Reported	5 · 3.4 Bulky purity and magnetic properties · Fig. 8b
compound 2 chiM T at room temperature	0.51 cm3 K mol-1	—	—	Text Exact Reported	4 · 3.4 Bulky purity and magnetic properties · Fig. 8b
compound 2 magnetic fit g	2.05	—	—	Text Exact Reported	6 · 3.4 Bulky purity and magnetic properties · Fig. 8b
compound 2 magnetic fit zj prime	-1.57 cm-1	—	—	Text Exact Reported	6 · 3.4 Bulky purity and magnetic properties · Fig. 8b

As-isolated bulk crystals of compound 2 · Powder

Yield based on Cu; CHN elemental analysis; IR measured with KBr pellets over 4000-400 cm-1.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
absence of carbonyl IR band for 2	no strong peaks around 1700 cm-1	—	—	Text Qualitative	2 · 3.1 Synthesis · Fig. S1
isolated yield of compound 2	0.0553 g (55% based on Cu)	—	—	Text Exact Reported	2 · 2.2 Synthesis