cMOF Evidence Base
Other — Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystals

Measurement evidence

Other

Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystals · Ambrogi E.K., Damacet P., Stolz R.M. et al. · ACS Nano · 2025 · 1383-1395

6 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

calculated reagent/oxidant concentration

ATR in situ air-bubbled Ni3(HHTP)2, room temperature · Thin Film

in situ ATR-FTIR reaction-cell concentrations

Temperature
298
Atmosphere
varied
Geometry
reaction cell
Context
pristine Ni3(HHTP)2
Measurement source
S32-S34 · Oxidant Concentrations · Table S10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
air/O2 saturated oxidant concentration275 uM——SI Table
Exact Reported		S32-S34 · Table S10 · Table S10
H2O2 oxidant concentration117 mM——SI Table
Exact Reported		S32-S34 · Table S10 · Table S10
HHTP final concentration7.4 mM——SI Table
Exact Reported		S32-S34 · Table S10 · Table S10
N2 oxidant concentration0 uM——SI Table
Exact Reported		S32-S34 · Table S10 · Table S10
Ni(OAc)2 final concentration14.8 mM——SI Table
Exact Reported		S32-S34 · Table S10 · Table S10
O2 replenishments for full conversionapproximately 43 times——Calculated From Reported
Approximate		S32-S34 · Table S10 · Table S10

gravimetric MOF yield

homogeneous DMF/water air plus H2O2 Ni3(HHTP)2, 85 C · Powder

bulk synthesis at 85 C, 18 h

Temperature
358
Atmosphere
as route
Context
pristine Ni3(HHTP)2
Measurement source
S11 · MOF Yields · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
average MOF yield21 +/- 5 %—+/- 5 %SI Table
Rounded Reported		S11 · Table S3 · Table S3

gravimetric MOF yield

heterogeneous water bubbled-air Ni3(HHTP)2, 85 C · Powder

bulk synthesis at 85 C, 18 h

Temperature
358
Atmosphere
as route
Context
pristine Ni3(HHTP)2
Measurement source
S11 · MOF Yields · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
average MOF yield24 +/- 10 %—+/- 10 %SI Table
Rounded Reported		S11 · Table S3 · Table S3

gravimetric MOF yield

homogeneous DMF/water bubbled-air Ni3(HHTP)2, 85 C · Powder

bulk synthesis at 85 C, 18 h

Temperature
358
Atmosphere
as route
Context
pristine Ni3(HHTP)2
Measurement source
S11 · MOF Yields · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
average MOF yieldMarked as a best value within this paper39 +/- 15 %—+/- 15 %SI Table
Rounded Reported		S11 · Table S3 · Table S3

gravimetric MOF yield

homogeneous DMF/water N2 plus H2O2 Ni3(HHTP)2, 85 C · Powder

bulk synthesis at 85 C, 18 h

Temperature
358
Atmosphere
as route
Context
pristine Ni3(HHTP)2
Measurement source
S11 · MOF Yields · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
average MOF yield19 +/- 7 %—+/- 7 %SI Table
Rounded Reported		S11 · Table S3 · Table S3

gravimetric MOF yield

homogeneous DMF/water bubbled-N2 Ni3(HHTP)2, 85 C · Powder

bulk synthesis at 85 C, 18 h

Temperature
358
Atmosphere
as route
Context
pristine Ni3(HHTP)2
Measurement source
S11 · MOF Yields · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
average MOF yield9 +/- 6 %—+/- 6 %SI Table
Rounded Reported		S11 · Table S3 · Table S3