Porosity — Highly Selective CO2 Electroreduction to CH4 by In Situ Generated Cu2O Single-Type Sites on a Conductive MOF: Stabilizing Key Intermediates with Hydrogen Bonding

Measurement evidence

Porosity

Highly Selective CO2 Electroreduction to CH4 by In Situ Generated Cu2O Single-Type Sites on a Conductive MOF: Stabilizing Key Intermediates with Hydrogen Bonding · Yi J.-D., Xie R., Xie Z.-L. et al. · Angewandte Chemie - International Edition · 2020 · 23641-23648

1 measurement group · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 sorption, BET, NL-DFT pore-size distribution, CO2 sorption

Gas sorption and porosity Density functional theory

Pristine CuHHTP black powder · Powder

N2 at 77 K; CO2 at 298 K

Temperature: 77; 298
Atmosphere: N2; CO2
Geometry: Micromeritics ASAP 2460 for N2/BET; Micromeritics ASAP 2020 for CO2
Context: pristine conductive MOF
Measurement source: p003 / 23643 · Results and Discussion · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface-area-like value for CuHHTP	184 cm3 g^-1	—	—	Text Exact Reported	p003 / 23643 · Figure S1a
CO2 adsorption uptake of CuHHTP at 298 K	16 cm3 g^-1 at 298 K	—	—	Text Exact Reported	p003 / 23643 · Figure S1c
Micropore size of CuHHTP	1.23 nm	—	—	Text Exact Reported	p003 / 23643 · Figure S1b