Other — Understanding Solvothermal Growth of Metal-Organic Framework Colloids for CO2Capture Applications

35 measurement groups · 35 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu0.3BTC-100-8 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.006	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-100-14 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.021	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-100-20 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.023	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-100-3 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.009	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-100-5 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.008	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-100-8 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.019	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-120-14 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.031	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-120-20 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.033	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-120-3 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.022	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-120-5 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.028	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-120-8 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.028	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-80-14 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.014	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-80-20 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.011	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-80-3 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.005	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-80-5 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.008	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu1BTC-80-8 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacity	0.008	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

CO2 pulse adsorption by temperature-programmed chemisorption

1Cu3BTC-100-8 · Powder

ASAP 2920; 200 mg sample degassed under He at 120 deg C for 30 min; 0.5 mL CO2 pulses repeatedly injected at 35 deg C and 1 atm until no further uptake.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 5; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake capacityMarked as a best value within this paper	0.035	—	—	Text Exact Reported	4420-4421 · Results and Discussion · Figure 5

Electrospray-differential mobility analysis (ES-DMA)

1Cu0.3BTC-100-8 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	151.0 +/- 0.5	—	+/- 0.5 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-100-14 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	182.9 +/- 2.9	—	+/- 2.9 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-100-20 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	187.6 +/- 3.1	—	+/- 3.1 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-100-3 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	165.9 +/- 3.3	—	+/- 3.3 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-100-5 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	174.2 +/- 6.3	—	+/- 6.3 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-100-8 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	176.4 +/- 4.3	—	+/- 4.3 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-120-14 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	189.5 +/- 1.7	—	+/- 1.7 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-120-20 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	193.4 +/- 2.0	—	+/- 2.0 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-120-3 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	177.6 +/- 2.5	—	+/- 2.5 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-120-5 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	181.8 +/- 0.5	—	+/- 0.5 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-120-8 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	186.5 +/- 1.9	—	+/- 1.9 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-80-14 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	169.8 +/- 1.6	—	+/- 1.6 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-80-20 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	172.1 +/- 3.6	—	+/- 3.6 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-80-3 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	154.0 +/- 1.6	—	+/- 1.6 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-80-5 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	158.1 +/- 1.3	—	+/- 1.3 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu1BTC-80-8 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	162.4 +/- 0.3	—	+/- 0.3 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

1Cu3BTC-100-8 · Powder

Cu-MOF colloids diluted 10-1000 times in dilute nitric acid aqueous solution (pH 5), electrosprayed, neutralised with Po-210, classified by DMA and counted by CPC; Table 2 reports dp,m,avg.

Context: pristine Cu-MOF colloid
Measurement source: 4417 · Materials and Methods · Figure 1; Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	187.8 +/- 5.3	—	+/- 5.3 nm	Table Exact Reported	4418 · Results and Discussion · Table 2

Electrospray-differential mobility analysis (ES-DMA)

3Cu1BTC-100-8 · Powder

SI Section 7 copper-source variant; mobility size distribution in Figure S13a.

Context: pristine Cu-MOF colloid
Measurement source: S16 · Material characterization of the Cu-MOF prepared by a different amount of copper · Figure S13a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average mobility particle size dp,m,avg	181.7 +/- 0.5	—	+/- 0.5 nm	Text Exact Reported	S16 · Material characterization of the Cu-MOF prepared by a different amount of copper · Figure S13a