Porosity — Understanding Solvothermal Growth of Metal-Organic Framework Colloids for CO2Capture Applications

18 measurement groups · 52 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu0.3BTC-100-8 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	622 +/- 124	—	+/- 124 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.17	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.51	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-100-14 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	913 +/- 46	—	+/- 46 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.31	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.74	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-100-20 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	976 +/- 29	—	+/- 29 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.32	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.8	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-100-3 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	645 +/- 104	—	+/- 104 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.21	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.33	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-100-5 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	743 +/- 44	—	+/- 44 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.25	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.52	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-100-8 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	842 +/- 61	—	+/- 61 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.32	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.59	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-120-14 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	1158 +/- 27	—	+/- 27 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.39	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.96	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-120-20 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface areaMarked as a best value within this paper	1201 +/- 48	—	+/- 48 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.43	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.98	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-120-3 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	887 +/- 51	—	+/- 51 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.3	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.68	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-120-5 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	1145 +/- 78	—	+/- 78 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.37	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.92	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-120-8 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	1164 +/- 28	—	+/- 28 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.39	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.94	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-80-14 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	766 +/- 6	—	+/- 6 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.26	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.47	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-80-20 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	796 +/- 86	—	+/- 86 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.26	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.46	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-80-3 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	565 +/- 89	—	+/- 89 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.22	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.31	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-80-5 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	704 +/- 46	—	+/- 46 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.24	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.34	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu1BTC-80-8 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	731 +/- 111	—	+/- 111 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.23	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.34	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET, t-plot and BJH analyses

Gas sorption and porosity

1Cu3BTC-100-8 · Powder

Samples degassed at 120 deg C for at least 8 h; BET surface area from P/P0=0.05-0.3; Vpore from micropore plus mesopore volume; Vmicro from t-plot.

Context: pristine Cu-MOF colloid
Measurement source: 4418 · Materials and Methods · Figure 3; Table 2; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	1153 +/- 34	—	+/- 34 m2/g	Table Exact Reported	4418 · Results and Discussion · Table 2
micropore volume Vmicro	0.38	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2
total pore volume Vpore	0.93	—	—	Table Exact Reported	4418 · Results and Discussion · Table 2

N2 adsorption-desorption; BET analysis

Gas sorption and porosity

3Cu1BTC-100-8 · Powder

SI Section 7 copper-source variant; N2 adsorption-desorption isotherm in Figure S13b.

Context: pristine Cu-MOF colloid
Measurement source: S16 · Material characterization of the Cu-MOF prepared by a different amount of copper · Figure S13b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET specific surface area	1032	—	—	Text Exact Reported	S16 · Material characterization of the Cu-MOF prepared by a different amount of copper · Figure S13b