cMOF Evidence Base
Diffraction Structure — Super Proton Conductivity Through Control of Hydrogen-Bonding Networks in Flexible Metal–Organic Frameworks

Measurement evidence

Diffraction Structure

Super Proton Conductivity Through Control of Hydrogen-Bonding Networks in Flexible Metal–Organic Frameworks · Kwon N.H., Han S., Kim J. et al. · Small · 2023 · 2301122

2 measurement groups · 23 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Le Bail refinement of PXRD

X-ray diffraction and scattering

Im@MIL-88B-LB · Powder

Cell parameters and space groups for dried/as-synthesised MIL-88B and imidazole-loaded SB/LB states.

Context
structure assignment
Measurement source
S11-S13 · Results and Discussion · Figure S6; Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
As-synthesised MIL-88B cell parameter a11.0——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Dried MIL-88B cell parameter a9.5——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-LB cell parameter a16.36——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-SB cell parameter a11.62——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
As-synthesised MIL-88B cell parameter b11.0——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Dried MIL-88B cell parameter b9.5——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-LB cell parameter b16.36——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-SB cell parameter b11.62——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
As-synthesised MIL-88B cell parameter c19.0——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Dried MIL-88B cell parameter c19.0——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-LB cell parameter c15.54——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-SB cell parameter c18.83——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
As-synthesised MIL-88B unit-cell volume1998.2——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Dried MIL-88B unit-cell volume1485.0——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-LB unit-cell volume3597.7——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-SB unit-cell volume2200.2——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
As-synthesised MIL-88B space groupP-62c——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Dried MIL-88B space groupP-62c——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-LB space groupP63/mmc——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-SB space groupP63/mmc——SI Table
Exact Reported		S13 · Results and Discussion · Table S3
Im@MIL-88B-LB cell-volume expansion from dried state142.22%——Text
Exact Reported		p002 · 2.2 · Table S3
Im@MIL-88B-SB cell-volume expansion from dried state48.15%——Text
Exact Reported		p002 · 2.2 · Table S3

Powder X-ray diffraction (PXRD)

X-ray diffraction and scattering

MIL-88B · Powder

Cu Kalpha1 radiation, 2 theta 5-40 deg, 0.01 deg step, 5 deg/min; used for phase and breathing assignments.

Atmosphere
ambient/dry/humid as specified
Context
framework and loaded samples
Measurement source
S4 · Characterization · Figures 1, S5-S7, S13, S18
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
PXRD stability after water immersion and EISPXRD patterns remain consistent after water immersion and EIS——Qualitative
Qualitative		p004 · 2.3 · Figure S18