Electrochemistry Application — In Situ Growth of Lithiophilic MOF Layer Enabling Dendrite-free Lithium Deposition

14 measurement groups · 55 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Coulombic efficiency of Li plating/stripping

Cu-MOF-30 min · Electrode

Deposit 1 mAh cm^-2 Li at 0.5 mA cm^-2 and strip to 0.5 V; comparison of Cu, Cu-MOF-30 min and Cu-MOF-24 h over 300 cycles.

Temperature: room temperature
Atmosphere: 1 M LiTFSI in DOL/DME (1:1 v/v) with 0.1 M LiNO3
Geometry: CR2025 half cell; Cu or Cu-MOF working electrode, Li counter electrode
Context: Cu-MOF/Cu current collectors compared with Cu foil control
Measurement source: p016 / SI p.4 · Transparent Methods - Electrochemical measurements · Figure 3C

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu foil CE fluctuation onset	CEs of Cu foil display tremendous fluctuation after just 53 cycles	—	after just	Text Exact Reported	p005 / journal p.4 · Li Plating/Stripping Behavior · Figure 3C
Cu-MOF-24 h CE initial stability	CEs stable in the initial 120 cycles then scatter/decline	—	initial	Text Exact Reported	p006 / journal p.5 · Li Plating/Stripping Behavior · Figure 3C
Cu-MOF-30 min Coulombic efficiency over 300 cyclesMarked as a best value within this paper	above 97.1% during 300 cycles	—	above	Text Approximate	p005 / journal p.4 · Li Plating/Stripping Behavior · Figure 3C

Electrochemical impedance spectroscopy (EIS), equivalent-circuit fit

Impedance spectroscopy

Li@Cu-MOF-30 min · Electrode

Nyquist plots of Li||Li@Cu, Li||Li@Cu-MOF-30 min and Li||Li@Cu-MOF-24 h before and after 10 and 100 cycles.

Temperature: room temperature
Atmosphere: Symmetric-cell electrolyte as reported in methods
Geometry: BioLogic VMP3 electrochemical workstation; symmetric cells
Context: Li-loaded Cu-MOF and Cu electrodes
Measurement source: p006 / journal p.5 · Li Plating/Stripping Behavior · Figure S2D and Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Rct, Li\|\|Li@Cu before cycling	68.33 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu after 10 cycles	38.77 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu after 100 cycles	4.73 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu-MOF-24 h before cycling	95.42 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu-MOF-24 h after 10 cycles	137.40 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu-MOF-24 h after 100 cycles	137.83 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu-MOF-30 min before cycling	66.31 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu-MOF-30 min after 10 cyclesMarked as a best value within this paper	35.83 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1
Rct, Li\|\|Li@Cu-MOF-30 min after 100 cyclesMarked as a best value within this paper	37.39 ohm	—	—	SI Table Exact Reported	p019 / SI p.7 · Table S1 · Table S1

Exchange current density calculated from Rct

Li@Cu-MOF-30 min · Electrode

j0 = RT/nFRct using Table S1 Rct after 10 cycles for Cu, Cu-MOF-30 min and Cu-MOF-24 h.

Temperature: room temperature
Geometry: Calculated from symmetric-cell EIS
Context: Li-loaded Cu-MOF and Cu electrodes
Measurement source: p007 / journal p.6 · Li Plating/Stripping Behavior · Equation 1 and Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Exchange current density after 10 cycles, Cu	0.586 mA cm^-2	—	—	Calculated From Reported Exact Reported	p007 / journal p.6 · Li Plating/Stripping Behavior · Equation 1
Exchange current density after 10 cycles, Cu-MOF-24 h	0.165 mA cm^-2	—	—	Calculated From Reported Exact Reported	p007 / journal p.6 · Li Plating/Stripping Behavior · Equation 1
Exchange current density after 10 cycles, Cu-MOF-30 minMarked as a best value within this paper	0.635 mA cm^-2	—	—	Calculated From Reported Exact Reported	p007 / journal p.6 · Li Plating/Stripping Behavior · Equation 1

LiFePO4 full-cell cycling at 0.5 C

Li@Cu-MOF-30 min · Electrode

Li@Cu||LFP, Li@Cu-MOF-30 min||LFP and Li@Cu-MOF-24 h||LFP full cells at 0.5 C for 100 cycles.

Temperature: room temperature
Atmosphere: 1 M LiTFSI in DOL/DME (1:1 v/v) with 0.1 M LiNO3
Geometry: Full cell with Li-loaded current collector anode and LFP cathode
Context: Li@Cu-MOF anodes compared with Li@Cu; same cathode and electrolyte
Measurement source: p009 / journal p.8 · Assessment of Electrochemical Performance in Full Cells · Figure 5A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@Cu\|\|LFP capacity after 100 cycles at 0.5 C	100.8 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5A
Li@Cu\|\|LFP capacity retention after 100 cycles at 0.5 C	70.1%	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5A
Li@Cu-MOF-24 h\|\|LFP capacity after 100 cycles at 0.5 C	109.5 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5A
Li@Cu-MOF-24 h\|\|LFP capacity retention after 100 cycles at 0.5 C	77.7%	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5A
Li@Cu-MOF-30 min\|\|LFP capacity after 100 cycles at 0.5 CMarked as a best value within this paper	119.8 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5A
Li@Cu-MOF-30 min\|\|LFP CE after 100 cycles at 0.5 CMarked as a best value within this paper	99.7%	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5A
Li@Cu-MOF-30 min\|\|LFP capacity retention after 100 cycles at 0.5 CMarked as a best value within this paper	85.1%	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5A

LiFePO4 full-cell cycling at 1 C

Li@Cu-MOF-30 min · Electrode

Li@Cu-MOF-30 min||LFP and Li@Cu||LFP full cells at 1 C for 200 cycles.

Temperature: room temperature
Atmosphere: 1 M LiTFSI in DOL/DME (1:1 v/v) with 0.1 M LiNO3
Geometry: Full cell with Li-loaded current collector anode and LFP cathode
Context: Li@Cu-MOF-30 min compared with Li@Cu
Measurement source: p009 / journal p.8 · Assessment of Electrochemical Performance in Full Cells · Figure S3B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@Cu\|\|LFP capacity after 200 cycles at 1 C	53.3 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure S3B
Li@Cu\|\|LFP capacity retention after 200 cycles at 1 C	53.8%	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure S3B
Li@Cu-MOF-30 min\|\|LFP capacity after 200 cycles at 1 CMarked as a best value within this paper	68.9 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure S3B
Li@Cu-MOF-30 min\|\|LFP capacity retention after 200 cycles at 1 CMarked as a best value within this paper	69.4%	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure S3B

Full-cell rate capability

Li@Cu-MOF-30 min · Electrode

Li@Cu-MOF-30 min||LFP at 0.1, 0.2, 0.5 and 1 C, then returned to lower rates.

Temperature: room temperature
Geometry: LFP full cell
Context: Li@Cu-MOF-30 min anode
Measurement source: p009 / journal p.8 · Assessment of Electrochemical Performance in Full Cells · Figure 5D-5E

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@Cu-MOF-30 min\|\|LFP average discharge capacity at 0.1 CMarked as a best value within this paper	148.2 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5D
Li@Cu-MOF-30 min\|\|LFP average discharge capacity at 0.2 C	129.9 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5D
Li@Cu-MOF-30 min\|\|LFP average discharge capacity at 0.5 C	110.1 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5D
Li@Cu-MOF-30 min\|\|LFP average discharge capacity at 1 C	74.2 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5D
Li@Cu-MOF-30 min\|\|LFP discharge capacity after return to 0.1 C	129.8 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5D
Li@Cu-MOF-30 min\|\|LFP discharge capacity after return to 0.2 C	118.6 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5D
Li@Cu-MOF-30 min\|\|LFP discharge capacity after return to 0.5 C	107.7 mAh g^-1	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5D

Full-cell charge-discharge voltage profiles

Galvanostatic cycling

Li@Cu-MOF-30 min · Electrode

Voltage difference between charge and discharge platforms for Li@Cu-MOF-30 min, Li@Cu-MOF-24 h and Li@Cu cells.

Temperature: room temperature
Geometry: LFP full cell
Context: Li@Cu-MOF anodes compared with Li@Cu
Measurement source: p009 / journal p.8 · Assessment of Electrochemical Performance in Full Cells · Figures 5B-5C

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Initial full-cell charge/discharge voltage difference, Li@Cu	150 mV	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5B
Initial full-cell charge/discharge voltage difference, Li@Cu-MOF-24 h	77 mV	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5B
Initial full-cell charge/discharge voltage difference, Li@Cu-MOF-30 minMarked as a best value within this paper	64 mV	—	—	Text Exact Reported	p009 / journal p.8 · Assessment of Electrochemical Performance · Figure 5B

Li nucleation overpotential from voltage dip to subsequent plateau

Cu-MOF-30 min · Electrode

Li plating on Cu, Cu-MOF-30 min and Cu-MOF-24 h at 0.5 mA cm^-2.

Temperature: room temperature
Atmosphere: CR2025 coin cells with LiTFSI/DOL-DME/LiNO3 electrolyte
Geometry: Half cell with Li metal counter electrode
Context: Cu-MOF/Cu current collectors compared with Cu foil control
Measurement source: p005 / journal p.4 · Li Plating/Stripping Behavior · Figure 3A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li nucleation overpotential on Cu foil	31 mV	—	—	Text Exact Reported	p005 / journal p.4 · Li Plating/Stripping Behavior · Figure 3A
Li nucleation overpotential on Cu-MOF-24 h	29 mV	—	—	Text Exact Reported	p005 / journal p.4 · Li Plating/Stripping Behavior · Figure 3A
Li nucleation overpotential on Cu-MOF-30 minMarked as a best value within this paper	22 mV	—	—	Text Exact Reported	p005 / journal p.4 · Li Plating/Stripping Behavior · Figure 3A

Galvanostatic Li plating/stripping profile cycling

Galvanostatic cycling

Cu-MOF-30 min · Electrode

Fixed plating capacity 1 mAh cm^-2 and current density 0.5 mA cm^-2; profiles followed for 300 cycles.

Temperature: room temperature
Atmosphere: LiTFSI/DOL-DME/LiNO3 electrolyte
Geometry: Half cell
Context: Cu-MOF/Cu current collectors compared with Cu foil control
Measurement source: p005 / journal p.4 · Li Plating/Stripping Behavior · Figures 3B and S2E-S2H

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu foil half-cell profile lifetime	Cu foil electrode can only realise a lifetime of 150 cycles	—	—	Text Exact Reported	p005 / journal p.4 · Li Plating/Stripping Behavior · Figure S2E-S2F
Cu-MOF-30 min plating/stripping profile stabilityMarked as a best value within this paper	Basically identical curves during whole 300 cycles	—	—	Text Exact Reported	p005 / journal p.4 · Li Plating/Stripping Behavior · Figure 3B

Li plating/stripping CE for alternate-solvent Cu-MOF coatings

Cu-MOF/E · Electrode

Cu-MOF/E, Cu-MOF/B and Cu-MOF/D electrodes in Li plating/stripping half cells.

Temperature: room temperature
Atmosphere: LiTFSI/DOL-DME/LiNO3 electrolyte
Geometry: Half cells
Context: Alternate solvent Cu-MOF/Cu current collectors
Measurement source: p009 / journal p.8 · The Universality and Effectiveness of the Synthesis Method · Figure S5I-S5K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Alternate-solvent Cu-MOF CE threshold	>97%	—	greater than	Text Approximate	p009 / journal p.8 · The Universality and Effectiveness of the Synthesis Method · Figure S5I-S5K

Long-term symmetric-cell cycling for alternate-solvent Cu-MOF coatings

Li@Cu-MOF-30 min · Electrode

Li@Cu-MOF/E, Li@Cu-MOF/B and Li@Cu-MOF/D symmetric cells.

Temperature: room temperature
Atmosphere: LiTFSI/DOL-DME/LiNO3 electrolyte
Geometry: Symmetric cells
Context: Alternate solvent Cu-MOF/Cu current collectors
Measurement source: p009 / journal p.8 · The Universality and Effectiveness of the Synthesis Method · Figure S5L-S5N

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Alternate-solvent Cu-MOF long-term cycling stability threshold	>2000 h	—	greater than	Text Approximate	p009 / journal p.8 · The Universality and Effectiveness of the Synthesis Method · Figure S5L-S5N

Long-term symmetric-cell Li plating/stripping at high current/high capacity

Li@Cu-MOF-30 min · Electrode

Li@Cu-MOF-30 min symmetric cell at 2 mA cm^-2 and 5 mAh cm^-2.

Temperature: room temperature
Atmosphere: LiTFSI/DOL-DME/LiNO3 electrolyte
Geometry: Symmetric cell
Context: Li@Cu-MOF-30 min only
Measurement source: p008 / journal p.7 · Electrochemical Testing · Figure S3A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@Cu-MOF-30 min high-loading stable cycling	350 h stable cycling at 2 mA cm^-2 and 5 mAh cm^-2	—	—	Text Exact Reported	p008 / journal p.7 · Electrochemical Testing · Figure S3A
Li@Cu-MOF-30 min high-loading overpotential	approximately 35 mV	—	approximately	Text Approximate	p008 / journal p.7 · Electrochemical Testing · Figure S3A

Long-term symmetric-cell Li plating/stripping

Li@Cu-MOF-30 min · Electrode

Li@Cu-, Li@Cu-MOF-30 min- and Li@Cu-MOF-24 h-based symmetric cells; electrodes preloaded with 2 mAh cm^-2 Li at 0.5 mA cm^-2.

Temperature: room temperature
Atmosphere: LiTFSI/DOL-DME/LiNO3 electrolyte
Geometry: Symmetric cell
Context: Li-loaded Cu-MOF electrodes compared with Li@Cu
Measurement source: p007 / journal p.6 · Electrochemical Testing · Figure 4A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@Cu symmetric-cell initial increase period before failure	overpotential continuously increases in the initial 623 h, followed by voltage drop/fluctuation	—	initial	Text Exact Reported	p007 / journal p.6 · Electrochemical Testing · Figure 4A
Li@Cu-MOF-24 h symmetric-cell stable cycling	1,070 h stable cycling	—	—	Text Exact Reported	p007 / journal p.6 · Electrochemical Testing · Figure 4A
Li@Cu-MOF-30 min symmetric-cell lifetimeMarked as a best value within this paper	over 2,500 h	—	over	Text Approximate	p007 / journal p.6 · Electrochemical Testing · Figure 4A
Li@Cu-MOF-30 min symmetric-cell overpotentialMarked as a best value within this paper	around 13.1 mV	—	around	Text Approximate	p007 / journal p.6 · Electrochemical Testing · Figure 4A

Symmetric-cell rate capability

Li@Cu-MOF-30 min · Electrode

Current densities 0.2, 0.5, 1, 2 and 5 mA cm^-2 at constant areal capacity 1 mAh cm^-2; then return to 0.2 mA cm^-2.

Temperature: room temperature
Atmosphere: LiTFSI/DOL-DME/LiNO3 electrolyte
Geometry: Symmetric cell
Context: Li@Cu-MOF-30 min compared with Li@Cu-MOF-24 h and Li@Cu
Measurement source: p008 / journal p.7 · Electrochemical Testing · Figure 4B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@Cu-MOF-30 min average overpotential at 0.2 mA cm^-2Marked as a best value within this paper	7.1 mV	—	—	Text Exact Reported	p008 / journal p.7 · Electrochemical Testing · Figure 4B
Li@Cu-MOF-30 min average overpotential at 0.5 mA cm^-2	12.2 mV	—	—	Text Exact Reported	p008 / journal p.7 · Electrochemical Testing · Figure 4B
Li@Cu-MOF-30 min average overpotential at 1 mA cm^-2	17.3 mV	—	—	Text Exact Reported	p008 / journal p.7 · Electrochemical Testing · Figure 4B
Li@Cu-MOF-30 min average overpotential at 2 mA cm^-2	28.1 mV	—	—	Text Exact Reported	p008 / journal p.7 · Electrochemical Testing · Figure 4B
Li@Cu-MOF-30 min average overpotential at 5 mA cm^-2	55.3 mV	—	—	Text Exact Reported	p008 / journal p.7 · Electrochemical Testing · Figure 4B
Li@Cu-MOF-30 min recovered overpotential after returning to 0.2 mA cm^-2	7.3 mV after rate returned to 0.2 mA cm^-2	—	—	Text Exact Reported	p008 / journal p.7 · Electrochemical Testing · Figure 4B