Complete recipeSource: Main
Route 1: Liquid Liquid Interface
main p.3 · Synthesis of [Zn2(INH)2(succ)2]n (1)
Metal precursorsZn(NO3)2.6H2O (0.297 g, 1 mmol)
Linker precursorsSuccinic acid (H2succ) (0.118 g, 1 mmol); isoniazid (0.137 g, 1 mmol)
SolventsWater (10 mL for Zn source); ethanol (10 mL for H2succ/Et3N solution; 10 mL for isoniazid solution); methanol/water 1:1 wash
AdditivesTriethylamine, Et3N (0.212 g, 2 mmol), used to neutralise succinic acid
AtmosphereAmbient; no inert atmosphere reported
Temperatureroom temperature (not explicitly stated)
Timeabout 168 h diffusion (one week)
Work-upCrystals separated mechanically under a microscope, washed with methanol/water (1:1), and dried.
ActivationNo activation reported.
Scalability contextLayer-diffusion single-crystal synthesis; small isolated yield of 0.026 g reported.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Zn(NO3)2.6H2O | 0.297 g, 1 mmol | main p.3 · Synthesis of [Zn2(INH)2(succ)2]n (1) |
| Linker | succinic acid (H2succ) | 0.118 g, 1 mmol | main p.3 · Synthesis of [Zn2(INH)2(succ)2]n (1) |
| Linker | isoniazid | 0.137 g, 1 mmol | main p.3 · Synthesis of [Zn2(INH)2(succ)2]n (1) |
| Base | Et3N | 0.212 g, 2 mmol | main p.3 · Synthesis of [Zn2(INH)2(succ)2]n (1) |
| Solvent | water | 10 mL | main p.3 · Synthesis of [Zn2(INH)2(succ)2]n (1) |
| Solvent | ethanol | 20 mL total in two 10 mL portions | main p.3 · Synthesis of [Zn2(INH)2(succ)2]n (1) |