Liu L., Zhang Y., Song Y. et al. · Inorganic Chemistry · 2024 · 10324-10334
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The Ni-HHTP@Co(OH)2//AC aqueous asymmetric device combines high energy density with 97.6% capacitance retention after 5000 cycles.
Caveat: Device comparison is against reported literature and a Ni-HHTP@CoP//AC internal comparator, not all possible device architectures.
article p. 10331-10332 · Results and Discussion · Figure 6g-h · Linked to 2 structured results
Ni-HHTP@Co(OH)2 is the best-performing electrode in the extracted series, reaching 435.64 F g-1 at 1 A g-1 and 390 F g-1 at 5 A g-1.
Caveat: Performance is supercapacitor-specific, not a direct electrical conductivity measurement.
article p. 10332 · Conclusions · Linked to 4 structured results
M-HHTP@Co3O4 composites show the weakest capacitance among the three substrate families, attributed to uneven Co3O4 morphology and agglomeration from micromagnetism.
Caveat: Agglomeration explanation is author interpretation based on SEM/morphology.
article p. 10331 · Results and Discussion · Figure 5g; Table S4 · Linked to 3 structured results
M-HHTP conductive MOFs were successfully grown in situ on Co(OH)2, CoP, and Co3O4 nanosheets, forming the reported composite series.
Caveat: Some phase assignments are supported by composite PXRD/FTIR/XPS rather than single-crystal structures.
article p. 10326-10329 · Results and Discussion · Figures 1-4 · Linked to 3 structured results
The authors attribute improved energy-storage behaviour to coupling between Ni-HHTP and cobalt-based substrates, forming effective charge-transfer/diffusion channels along Ni-HHTP 1D channels.
Caveat: Mechanistic interpretation is inferred from morphology, CV kinetics and EIS; no direct electronic conductivity value is reported.
article p. 10329-10331 · Results and Discussion · Figures 5-6 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Activated carbon YEC-8 | ACcarbon | unknown · UnknownCommercial activated carbon negative electrode material. | SI p. 12 · Asymmetric supercapacitor assembly and measurements |
| Co3O4 | Co3O4cobalt oxide | 2D · UnknownCalcined nanosheets with morphology similar to Co(OH)2 but fractured/agglomerating surface. | article p. 10326 · Results and Discussion · Figure S1c |
| Co-HHTPBrowse family: Co₃(HHTP)₂ / Co–HHTP | M-HHTP, M = Co; HHTP ligandCo2+ nodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · PristineConductive HHTP framework; SEM showed random nanorods. | article p. 10324 · Abstract |
| Co-HHTP@Co3O4Browse family: Co₃(HHTP)₂ / Co–HHTP | Co-HHTP@Co3O4 compositeCo2+ HHTP framework grown on Co3O4 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Co-HHTP@Co(OH)2Browse family: Co₃(HHTP)₂ / Co–HHTP | Co-HHTP@Co(OH)2 compositeCo2+ HHTP framework grown on Co(OH)2 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Co-HHTP@CoPBrowse family: Co₃(HHTP)₂ / Co–HHTP | Co-HHTP@CoP compositeCo2+ HHTP framework grown on CoP · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Co(OH)2 | Co(OH)2Co hydroxide | 2D · UnknownHydrothermally prepared nanosheets, diameter 80-200 nm. | article p. 10326 · Results and Discussion · Figure S1a |
| CoP | CoPcobalt phosphide | 2D · UnknownFolded CoP nanosheets obtained by phosphorization and sonication of Co(OH)2. | article p. 10326 · Results and Discussion · Figure S1b |
| Ni-HHTPBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | M-HHTP, M = Ni; HHTP ligandNi2+ nodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · PristineConductive HHTP framework; Ni-HHTP shows nanorod clusters and 1D channels along [001]. | article p. 10324 · Abstract |
| Ni-HHTP@Co3O4Browse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-HHTP@Co3O4 compositeNi2+ HHTP framework grown on Co3O4 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Ni-HHTP@Co(OH)2Browse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-HHTP@Co(OH)2 compositeNi2+ HHTP framework grown on Co(OH)2 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Ni-HHTP@Co(OH)2//AC asymmetric supercapacitorBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-HHTP@Co(OH)2 positive electrode // activated carbon negative electrodeNi-HHTP@Co(OH)2 and AC electrodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | unknown · CompositeAqueous asymmetric supercapacitor assembled in 3 M KOH. | article p. 10331 · Results and Discussion · Figure 6d-h |
| Ni-HHTP@CoPBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-HHTP@CoP compositeNi2+ HHTP framework grown on CoP · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| Ni-HHTP@CoP//AC asymmetric supercapacitorBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-HHTP@CoP positive electrode // activated carbon negative electrodeNi-HHTP@CoP and AC electrodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | unknown · CompositeAqueous asymmetric supercapacitor used for cycling comparison. | article p. 10332 · Results and Discussion · Figure S25 |
| NiCo-HHTPBrowse family: Ni/Co–HHTP family | M-HHTP, M = NiCo (Ni2+/Co2+ = 1:1); HHTP ligandmixed Ni2+/Co2+ nodes · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · PristineMixed-metal conductive HHTP framework; shorter agglomerated nanorods. | article p. 10326 · Results and Discussion · Figure S1 |
| NiCo-HHTP@Co3O4Browse family: Ni/Co–HHTP family | NiCo-HHTP@Co3O4 compositeNi2+/Co2+ HHTP framework grown on Co3O4 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| NiCo-HHTP@Co(OH)2Browse family: Ni/Co–HHTP family | NiCo-HHTP@Co(OH)2 compositeNi2+/Co2+ HHTP framework grown on Co(OH)2 · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
| NiCo-HHTP@CoPBrowse family: Ni/Co–HHTP family | NiCo-HHTP@CoP compositeNi2+/Co2+ HHTP framework grown on CoP · HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene | 2D · CompositeIn situ grown conductive M-HHTP nanoarrays/nanorods on a 2D cobalt-based compound substrate. | article p. 10326 · Results and Discussion · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Activated carbon AC YEC-8research_0688__mat__activated_carbon | Electrode · Composite Component · Unknown | commercial AC mixed with acetylene black and PTFE on nickel foamnickel foam | SI p. 12 · Asymmetric supercapacitor assembly and measurements |
| Co3O4research_0688__mat__co3o4 | Nanosheet · Pristine Control · Unknown | calcined nanosheets similar to Co(OH)2 | article p. 10326 · Results and Discussion · Figure S1a-c |
| Co-HHTPresearch_0688__mat__co_hhtp | Powder · Pristine Control · Pristine Framework | random nanorods | article p. 10326 · Results and Discussion · Figure S1d-f |
| Co-HHTP@Co3O4research_0688__mat__co_hhtp_co3o4 | Electrode · Composite Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCo3O4 | article p. 10326 · Results and Discussion · Figure 1 |
| Co-HHTP@Co3O4-0.5research_0688__mat__co_hhtp_co3o4 | Electrode · Composite Sample · Composite | prepared with halved substrate/metal/linker masses relative to the full-loading routeCo3O4 | article p. 10327 · Results and Discussion · Figure S5 |
| Co-HHTP@Co(OH)2research_0688__mat__co_hhtp_cooh2 | Electrode · Composite Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCo(OH)2 | article p. 10326 · Results and Discussion · Figure 1 |
| Co-HHTP@Co(OH)2-0.5research_0688__mat__co_hhtp_cooh2 | Electrode · Composite Sample · Composite | prepared with halved substrate/metal/linker masses relative to the full-loading routeCo(OH)2 | article p. 10327 · Results and Discussion · Figure S5 |
| Co-HHTP@CoPresearch_0688__mat__co_hhtp_cop | Electrode · Composite Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCoP | article p. 10326 · Results and Discussion · Figure 1 |
| Co-HHTP@CoP-0.5research_0688__mat__co_hhtp_cop | Electrode · Composite Sample · Composite | prepared with halved substrate/metal/linker masses relative to the full-loading routeCoP | article p. 10327 · Results and Discussion · Figure S5 |
| Co(OH)2research_0688__mat__cooh2 | Nanosheet · Pristine Control · Unknown | 2D nanosheets, 80-200 nm | article p. 10326 · Results and Discussion · Figure S1a-c |
| CoPresearch_0688__mat__cop | Nanosheet · Pristine Control · Unknown | folded nanosheets from phosphorized Co(OH)2 | article p. 10326 · Results and Discussion · Figure S1a-c |
| Ni-HHTPresearch_0688__mat__ni_hhtp | Powder · Pristine Control · Pristine Framework | nanorod clusters | article p. 10326 · Results and Discussion · Figure S1d-f |
| Ni-HHTP@Co3O4research_0688__mat__ni_hhtp_co3o4 | Electrode · Target Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCo3O4 | article p. 10326 · Results and Discussion · Figure 1 |
| Ni-HHTP@Co3O4-0.5research_0688__mat__ni_hhtp_co3o4 | Electrode · Composite Sample · Composite | prepared with halved substrate/metal/linker masses relative to the full-loading routeCo3O4 | article p. 10327 · Results and Discussion · Figure S5 |
| Ni-HHTP@Co(OH)2research_0688__mat__ni_hhtp_cooh2 | Electrode · Target Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCo(OH)2 | article p. 10326 · Results and Discussion · Figure 1 |
| Ni-HHTP@Co(OH)2//ACresearch_0688__mat__ni_hhtp_cooh2_ac_device | Electrode · Target Sample · Composite | aqueous asymmetric supercapacitor in 3 M KOHnickel foam | article p. 10331 · Results and Discussion · Figure 6d-h |
| Ni-HHTP@Co(OH)2-0.5research_0688__mat__ni_hhtp_cooh2 | Electrode · Composite Sample · Composite | prepared with halved substrate/metal/linker masses relative to the full-loading routeCo(OH)2 | article p. 10327 · Results and Discussion · Figure S5 |
| Ni-HHTP@CoPresearch_0688__mat__ni_hhtp_cop | Electrode · Target Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCoP | article p. 10326 · Results and Discussion · Figure 1 |
| Ni-HHTP@CoP//ACresearch_0688__mat__ni_hhtp_cop_ac_device | Electrode · Composite Sample · Composite | aqueous asymmetric supercapacitor in 3 M KOHnickel foam | article p. 10332 · Results and Discussion · Figure S25 |
| Ni-HHTP@CoP-0.5research_0688__mat__ni_hhtp_cop | Electrode · Composite Sample · Composite | prepared with halved substrate/metal/linker masses relative to the full-loading routeCoP | article p. 10327 · Results and Discussion · Figure S5 |
| NiCo-HHTPresearch_0688__mat__nico_hhtp | Powder · Pristine Control · Mixed Metal | short agglomerated mixed-metal nanorods | article p. 10326 · Results and Discussion · Figure S1d-f |
| NiCo-HHTP@Co3O4research_0688__mat__nico_hhtp_co3o4 | Electrode · Composite Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCo3O4 | article p. 10326 · Results and Discussion · Figure 1 |
| NiCo-HHTP@Co(OH)2research_0688__mat__nico_hhtp_cooh2 | Electrode · Composite Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCo(OH)2 | article p. 10326 · Results and Discussion · Figure 1 |
| NiCo-HHTP@CoPresearch_0688__mat__nico_hhtp_cop | Electrode · Composite Sample · Composite | in situ M-HHTP growth on presynthesized cobalt compound; full reagent loadingCoP | article p. 10326 · Results and Discussion · Figure 1 |