Complete recipeSource: Main
Route 1: Liquid Liquid Interface
6-7 · Synthesis of Compounds 1 and 2 · Figure 14
Metal precursorsCu(NO3)2.3H2O (24.16 mg, 0.1 mmol) in water (1 mL)
Linker precursors4,4'-BPY (15.619 mg, 0.1 mmol) in methanol (1 mL); HDABA (21.726 mg, 0.1 mmol) in ethanol (1 mL)
Solventswater, methanol, ethanol, water-methanol mixed solvent
AdditivesEt3N (10.119 mg, 0.1 mmol) to neutralise HDABA
Atmospherenot specified
Temperatureroom temperature
Time168
Substrate orientationlayered diffusion in glass vessel; crystals deposited on glass wall
Work-upCrystals separated mechanically under a microscope, washed with methanol/water (1:1), and dried.
Activationdried; no separate activation reported
Scalability contextLayered diffusion single-crystal route; no scale-up route reported.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cu(NO3)2.3H2O | 24.16 mg, 0.1 mmol · in 1 mL aqueous solution | 6-7 · Synthesis of Compounds 1 and 2 · Figure 14 |
| Linker | 4,4-BPY | 15.619 mg, 0.1 mmol · in 1 mL methanol | 6-7 · Synthesis of Compounds 1 and 2 · Figure 14 |
| Linker | HDABA | 21.726 mg, 0.1 mmol · in 1 mL ethanol | 6-7 · Synthesis of Compounds 1 and 2 · Figure 14 |
| Base | Et3N | 10.119 mg, 0.1 mmol | 6-7 · Synthesis of Compounds 1 and 2 · Figure 14 |
| Solvent | water-methanol mixed solvent | Not specified | 6-7 · Synthesis of Compounds 1 and 2 · Figure 14 |