Wang S., Park S.S., Buru C.T. et al. · Nature Communications · 2020 · 2495
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Ag+-stabilized PCN-222 2D superlattices photocatalyse selective CEES oxidation more efficiently than bulk PCN-222 under the reported conditions.
Caveat: Conversion values at 360 min are visually estimated from Fig. 5b; the text states higher efficiency qualitatively but does not tabulate conversions.
6 · Photocatalytic activity · Fig. 5 · Linked to 3 structured results
The paper does not report electrical conductivity, charge mobility, Seebeck coefficient, power factor, electrochemical conductivity or device transport measurements for the MOFs.
Caveat: Extraction covered main text and SI; application data are photocatalytic.
1 · Abstract
DNA-functionalised UiO-66 MOF PAEs form fcc, bcc and MOF-Au CsCl-type colloidal superlattices verified by SAXS and microscopy.
Caveat: The 20 nm Au CsCl assembly contains a small AlB2 impurity phase.
3-4 · Colloidal crystal engineering with MOF PAEs · Fig. 3 · Linked to 4 structured results
The internal pores of UiO-66 and PCN-222 remain accessible after DNA modification, although BET surface area decreases.
Caveat: PCN-222 shows a larger decrease attributed to possible DNA adsorption in mesopores.
3 · Results · Supplementary Figs. 11 and 12 · Linked to 4 structured results
MOF nanoparticle shape influences the resulting superlattice symmetry: octahedral UiO-66 gives bcc lattices, while PCN-222 nanorods form 2D hexagonal or tetragonal lattices depending on DNA linker design.
Caveat: The evidence is structural; transport consequences are not measured.
5 · Building block shape as a structure-influencing factor · Fig. 4 · Linked to 3 structured results
Phosphate/phosphonate-PEG-N3 passivation followed by DBCO-DNA click functionalisation provides colloidally stable MOF PAEs suitable for programmed DNA crystallisation.
Caveat: Demonstrated for Zr-based UiO-66 and PCN-222 nanoparticles; not a conductivity claim.
2-3 · Results · Figs. 1-2 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Ag-stabilized PCN-222 2D nanorod superlatticeBrowse family: PCN-222 / MOF-545 | PCN-222 nanorods + DNA linkers + Ag+ stabilizationPCN-222 Zr6 clusters; Ag+ stabilises DNA bonds · TCPP porphyrin linkers and DNA linker strands | 2D · CompositeAg+-stabilized PCN-222 nanorod superlattice retaining PCN-222 crystallinity after thermal/chemical treatments and catalysis. | 6 · Photocatalytic activity of the 2D PCN-222 nanorod superlattices · Fig. 5 |
| Ag+ ion and single-strand DNA control | Ag+ + single-strand DNAsingle-strand DNA | unknown · UnknownNon-MOF photocatalysis control used in CEES oxidation. | 6 · Fig. 5 caption · Fig. 5b |
| PCN-222 / MOF-545 zirconium porphyrinic MOF nanorodsBrowse family: PCN-222 / MOF-545 | Zr6O8(H2O)8(TCPP-H2)2Zr6 secondary building units · TCPP-H2 = tetrakis(4-carboxyphenyl)porphyrin linker | 3D · PristineRod-shaped porphyrinic zirconium MOF, also referred to as PCN-222/MOF-545, assembled into 2D hexagonal or tetragonal superlattices. | 4 · Building block shape as a structure-influencing factor · Fig. 4d |
| UiO-66 zirconium MOF nanoparticles | Zr6O4(OH)4(BDC)6; SI synthesis headings give [Zr6O4(OH)4(BDC)12]Zr6O4(OH)4 clusters / Zr6 secondary building units · BDC = 1,4-benzenedicarboxylate / terephthalic acid | 3D · PristineUiO-66 nanoparticles used as spherical and octahedral programmable atom equivalents; PXRD matches simulated UiO-66 before and after DNA functionalisation. | 2 · Results - Synthesis of uniform and colloidally stable MOF PAEs |
| UiO-66-Au DNA-linked CsCl hybrid superlattice | UiO-66 nanoparticles + Au nanoparticles + DNA linkersUiO-66 Zr6 clusters plus Au nanoparticle cores · UiO-66 BDC linkers; DBCO/thiol oligonucleotide surface linkers | 3D · CompositeCsCl-type (Pm-3m) binary colloidal superlattice of UiO-66 PAEs and Au PAEs. | 4 · Colloidal crystal engineering with MOF PAEs · Fig. 3d-f |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Ag+ and single-strand DNA controlresearch_0704__mat__mat_non_mof_control | Unknown · Pristine Control · Unknown | Control group for CEES photooxidation. | 6 · Fig. 5 caption · Fig. 5b |
| Ag+-stabilized PCN-222 2D superlattice photocatalystresearch_0704__mat__mat_ag_pcn222_lattice | Powder · Target Sample · Composite | Assembled PCN-222 superlattice solvent-exchanged into NaClO4/SDS, treated with AgNO3 in the dark, then exchanged with water and methanol. | 11 · Preparation of PCN-222 superlattice stabilized with Ag+ · Supplementary Figs. 21-24 |
| bulk PCN-222 single crystal controlresearch_0704__mat__mat_pcn222 | Single Crystal · Pristine Control · Pristine Framework | Micron-sized PCN-222 single crystal used as photocatalysis comparison at the same porphyrin loading.micron-sized | 6 · Photocatalytic activity · Fig. 5b |
| PCN-222 2D hexagonal nanorod superlatticeresearch_0704__mat__mat_pcn222 | Powder · Target Sample · Composite | PCN-222 PAEs assembled with self-complementary DNA linkers. | 5 · Building block shape as a structure-influencing factor · Fig. 4e-h |
| PCN-222/MOF-545 nanorod nanoparticlesresearch_0704__mat__mat_pcn222 | Powder · Pristine Control · Pristine Framework | Dark purple rod-shaped PCN-222/MOF-545 nanoparticles after centrifugation and DMF solvent exchange. | 4 · Synthesis of PCN-222/MOF-545 NPs · Supplementary Fig. 8 |
| DNA-PEG5k-functionalised PCN-222 PAEsresearch_0704__mat__mat_pcn222 | Powder · Target Sample · Guest Loaded | PCN-222 nanorods passivated with phosphate-PEG5k-N3 and functionalised with DBCO-TEG DNA. | 6 · DNA functionalization of MOF NPs |
| PCN-222 2D tetragonal nanorod superlatticeresearch_0704__mat__mat_pcn222 | Powder · Target Sample · Composite | Two batches of PCN-222 nanorods with complementary DNA linkers combined and annealed. | 5 · Building block shape as a structure-influencing factor · Fig. 4e-i |
| 37 nm UiO-66 / 20 nm Au CsCl superlatticeresearch_0704__mat__mat_uio66_au_hybrid | Powder · Composite Sample · Composite | Complementary DNA-functionalised 37 nm UiO-66 PAEs and 20 nm Au PAEs assembled in a 1:1 ratio. | 4 · Colloidal crystal engineering with MOF PAEs · Fig. 3e-f |
| 37 nm UiO-66 / 40 nm Au CsCl superlatticeresearch_0704__mat__mat_uio66_au_hybrid | Powder · Composite Sample · Composite | Complementary DNA-functionalised 37 nm UiO-66 PAEs and 40 nm Au PAEs assembled in a 1:1 ratio. | 4 · Colloidal crystal engineering with MOF PAEs · Fig. 3d |
| UiO-66 bcc MOF-MOF superlatticeresearch_0704__mat__mat_uio66 | Powder · Target Sample · Composite | Two batches of DNA-functionalised 37 nm UiO-66 NPs with complementary sticky ends assembled and annealed. | 3 · Colloidal crystal engineering with MOF PAEs · Fig. 3b-c |
| UiO-66 fcc MOF superlatticeresearch_0704__mat__mat_uio66 | Powder · Target Sample · Composite | DNA-functionalised 37 nm UiO-66 NPs assembled with self-complementary DNA sticky ends and annealed. | 3 · Colloidal crystal engineering with MOF PAEs · Fig. 3a-c |
| octahedral UiO-66 PAE bcc superlatticeresearch_0704__mat__mat_uio66 | Powder · Target Sample · Composite | Octahedral UiO-66 PAEs with self-complementary GCGC sticky ends assembled with DNA linkers. | 5 · Building block shape as a structure-influencing factor · Fig. 4c |
| octahedral UiO-66 nanoparticlesresearch_0704__mat__mat_uio66 | Powder · Pristine Control · Pristine Framework | Octahedral UiO-66 NPs made by acetic acid modulated solvothermal synthesis. | 4 · Synthesis of octahedral UiO-66 NPs · Supplementary Fig. 7 |
| DNA-PEG5k-functionalised UiO-66 PAEsresearch_0704__mat__mat_uio66 | Powder · Target Sample · Guest Loaded | UiO-66 nanoparticles passivated with phosphate-PEG5k-N3 and functionalised with DBCO-TEG DNA. | 3 · Synthesis of uniform and colloidally stable MOF PAEs · Fig. 2e |
| spherical UiO-66 nanoparticlesresearch_0704__mat__mat_uio66 | Powder · Pristine Control · Pristine Framework | As-synthesised and sucrose-gradient-purified spherical UiO-66 nanoparticles stored in anhydrous DMF or water depending on processing step. | 3 · Synthesis of spherical UiO-66 NPs · Supplementary Fig. 6 |