Other

dynamic light scattering (DLS)

Dynamic light scattering and zeta potential

DNA-PEG5k-functionalised UiO-66 PAEs · Powder

DLS analysis of UiO-66 NPs, PEG5k-modified UiO-66 NPs and DNA-functionalised UiO-66 PAEs in water or 0.5 M NaCl.

Context: surface-functionalised UiO-66 PAE colloidal stability
Measurement source: 3 · Synthesis of uniform and colloidally stable MOF PAEs · Fig. 2e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF-Au PAE aggregate melting transitionMarked as a best value within this paper	43 deg C	316.15 K	—	Text Exact Reported	3 · Results · Fig. 2f
DNA-functionalised UiO-66 PAE hydrodynamic sizeMarked as a best value within this paper	62 +/- 17 nm	—	+/- 17 nm	Text Exact Reported	3 · Results · Fig. 2e
PEG5k surface coverageMarked as a best value within this paper	~2 molecules/nm2	—	—	Text Approximate	3 · Results
PEG5k-modified UiO-66 hydrodynamic size	48 +/- 12 nm	—	+/- 12 nm	Text Exact Reported	3 · Results · Fig. 2e
PEG5k-modified UiO-66 polydispersity index	polydispersity index = 0.05	—	—	Text Exact Reported	3 · Results · Fig. 2e

CEES photooxidation monitored by GC-FID

Ag+-stabilized PCN-222 2D superlattice photocatalyst · Powder

MOF samples in 1 mL methanol, sealed microwave vial, O2 purged 20 min, CEES and internal standard added, TCPP loading 0.01 mol%, two 450 nm blue LEDs about 5 cm apart at 1.1 W/cm2.

Atmosphere: 1 atm O2 / O2-purged methanol
Context: Ag+-stabilized PCN-222 2D superlattice compared with bulk PCN-222 and Ag+ + DNA control
Measurement source: 12 · CEES Oxidation · Fig. 5b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CEES conversion by Ag+ and DNA control	no appreciable catalytic activity; plotted conversion near 0%	—	qualitative, trace remains near baseline	Qualitative Qualitative	6 · Fig. 5 caption · Fig. 5b
CEES conversion by Ag-PCN-222 lattice at 360 minMarked as a best value within this paper	approximately 84% conversion at 360 min	—	visual estimate from plotted point with error bar	Figure Axis Approximate	6 · Fig. 5 · Fig. 5b
CEES conversion by bulk PCN-222 at 360 min	approximately 72% conversion at 360 min	—	visual estimate from plotted point with error bar	Figure Axis Approximate	6 · Fig. 5 · Fig. 5b
photooxidation LED wavelength maximum	lambda_max = 450 nm	—	—	Text Exact Reported	12 · CEES Oxidation
photooxidation LED power density	1.1 W/cm2	—	—	Text Exact Reported	12 · CEES Oxidation
porphyrin loading for CEES oxidation	0.01 mol %	—	—	Text Exact Reported	12 · CEES Oxidation

2 measurement groups · 11 results