Diffraction Structure — Colloidal crystal engineering with metal–organic framework nanoparticles and DNA

7 measurement groups · 19 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ag+-stabilized PCN-222 2D superlattice photocatalyst · Powder

PXRD/SAXS after thermal treatment at 150 deg C for 48 h, MeOH reflux 24 h, 70 deg C water 24 h, pH 2 buffer 24 h, and after 5 catalytic cycles.

Atmosphere: dry state, MeOH, water, pH 2 buffer
Context: Ag+-stabilized PCN-222 superlattice stability
Measurement source: 11-12 · Thermal and chemical stability studies · Supplementary Figs. 21-24

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag-PCN-222 lattice crystallinity after catalysis	PXRD pattern retained after 5 catalytic cycles	—	—	Caption Qualitative	25 · Supplementary Figures · Supplementary Fig. 24
Ag-PCN-222 lattice chemical stability	preserved crystallinity after MeOH reflux 24 h, 70 deg C water 24 h, and pH 2 buffer 24 h	—	—	Caption Qualitative	24 · Supplementary Figures · Supplementary Fig. 22
Ag-PCN-222 lattice thermal stabilityMarked as a best value within this paper	thermally stable at 150 deg C for 48 h	423.15 K	—	Text Exact Reported	12 · Thermal and chemical stability studies · Supplementary Fig. 21

octahedral UiO-66 PAE bcc superlattice · Powder

4 uL samples on glow-discharged lacey carbon Cu grids, plunge-frozen in liquid ethane, imaged at -165 deg C and 200 kV.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
octahedral UiO-66 bcc lattice constantMarked as a best value within this paper	lattice constant = 180 nm	—	—	Text Exact Reported	5 · Building block shape as a structure-influencing factor · Fig. 4c

DNA-PEG5k-functionalised PCN-222 PAEs · Powder

Rigaku Smartlab PXRD of PCN-222 nanorods before and after DNA functionalisation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PCN-222 crystallinity after DNA functionalisation	PXRD pattern of PCN-222 PAEs matches PCN-222 NPs/simulated PCN-222	—	—	Qualitative Qualitative	15 · Supplementary Figures · Supplementary Fig. 5

DNA-PEG5k-functionalised UiO-66 PAEs · Powder

Rigaku Smartlab PXRD with Ni-filtered Cu-Kalpha radiation, lambda = 1.5418 A, 45 kV and 160 mA.

Context: UiO-66 before and after DNA functionalisation
Measurement source: 4 · Powder X-ray diffraction (PXRD) · Supplementary Fig. 4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
UiO-66 crystallinity after DNA functionalisation	PXRD pattern of UiO-66 PAEs matches UiO-66 NPs/simulated UiO-66	—	—	Qualitative Qualitative	15 · Supplementary Figures · Supplementary Fig. 4

37 nm UiO-66 / 40 nm Au CsCl superlattice · Powder

SAXS of binary UiO-66/Au DNA-linked superlattices.

Context: UiO-66-Au hybrid superlattices
Measurement source: 4 · Colloidal crystal engineering with MOF PAEs · Fig. 3d-f

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
37 nm UiO-66 / 20 nm Au CsCl lattice constantMarked as a best value within this paper	lattice constant = 79.6 nm	—	—	Text Exact Reported	4 · Colloidal crystal engineering with MOF PAEs · Fig. 3e
37 nm UiO-66 / 40 nm Au CsCl lattice constantMarked as a best value within this paper	lattice constant = 88.2 nm	—	—	Text Exact Reported	4 · Colloidal crystal engineering with MOF PAEs · Fig. 3d
AlB2 impurity a/b lattice constant	a = b = 76.5 nm	—	—	Text Exact Reported	4 · Colloidal crystal engineering with MOF PAEs · Fig. 3f
AlB2 impurity c lattice constant	c = 47.6 nm	—	—	Text Exact Reported	4 · Colloidal crystal engineering with MOF PAEs · Fig. 3f
MOF-Au single-crystal edge length	1-2 um edge length	—	range 1-2 um	Text Range	4 · Colloidal crystal engineering with MOF PAEs · Fig. 3i

PCN-222 2D tetragonal nanorod superlattice · Powder

PCN-222 nanorod superlattices characterised by SAXS and cryo-STEM; DNA linker length varied for tetragonal lattice spacing.

Context: PCN-222 2D nanorod superlattices
Measurement source: 5 · Building block shape as a structure-influencing factor · Fig. 4f-i

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PCN-222 tetragonal interparticle spacing with d120 linkerMarked as a best value within this paper	d120: 109 nm	—	—	Caption Exact Reported	5 · Fig. 4 caption · Fig. 4g
PCN-222 tetragonal interparticle spacing with d40 linker	d40: 77 nm	—	—	Caption Exact Reported	5 · Fig. 4 caption · Fig. 4g
PCN-222 tetragonal interparticle spacing with d80 linker	d80: 92 nm	—	—	Caption Exact Reported	5 · Fig. 4 caption · Fig. 4g
PCN-222 self-complementary nanorod lattice phase	2D close-packed hexagonal lattice	—	—	Text Qualitative	5 · Building block shape as a structure-influencing factor · Fig. 4h
PCN-222 complementary nanorod lattice phase	2D tetragonal lattice	—	—	Text Qualitative	5 · Building block shape as a structure-influencing factor · Fig. 4i

UiO-66 fcc MOF superlattice · Powder

SAXS at DND-CAT APS, X-ray wavelength 1.24 A (10 keV); 2D data radially averaged and indexed with Matlab.

Context: UiO-66 fcc and bcc colloidal superlattices
Measurement source: 9-10 · Small angle X-ray scattering (SAXS) studies · Fig. 3a-c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
spherical UiO-66 complementary superlattice phase	bcc, Im-3m	—	—	Text Qualitative	3 · Colloidal crystal engineering with MOF PAEs · Fig. 3a-c
best-monodispersity UiO-66 PAE sample sizeMarked as a best value within this paper	34 +/- 4 nm (CV = 11%)	—	+/- 4 nm; CV = 11%	Caption Exact Reported	4 · Fig. 3 caption · Fig. 3g
spherical UiO-66 self-complementary superlattice phase	fcc, Fm-3m	—	—	Text Qualitative	3 · Colloidal crystal engineering with MOF PAEs · Fig. 3a-c