Synthesis · Bimetallic synergy significantly enhances the photocatalytic performance of lanthanide porphyrin-based MOFs: Efficient photocatalytic oxidation of benzyl alcohol and benzylamine under mild conditions in air

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Solvothermal

2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs

Metal precursorsCo-TCPP; Nd(NO3)3.6H2O

Linker precursorsCo-TCPP

Solvents10 mL DMF; 5 mL ethanol; sulfuric acid aqueous solution VH2SO4:VH2O = 1:3

Additivessulfuric acid solution

Temperature100

Time12

Work-upCrystal precipitate collected and dried; workup otherwise as Ni-Nd PMOFs.

ActivationDried; exact temperature/time not specified.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	Co-TCPP	0.08 g	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Metal Source	Nd(NO3)3.6H2O	0.1 g	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Solvent	DMF	10 mL	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Acid	sulphuric acid solution	5 mL · VH2SO4:VH2O = 1:3	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Solvent	ethanol	5 mL	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs

Complete recipeSource: Both

Route 2: Solvothermal

2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP

Metal precursorsCo(NO3)2.6H2O

Linker precursorsH2TCPP

Solvents50 mL 0.2 mol/L NaOH(aq); 100 mL DMF

AdditivesNaOH

Temperature120

Time24

Work-upPrepared as Ni-TCPP; precipitate collected, washed with ethanol, dried at 80 C for 12 h.

ActivationDried at 80 C for 12 h.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	H2TCPP	0.5 g	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Base	sodium hydroxide solution	50 mL · 0.2 mol/L	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Metal Source	Co(NO3)2.6H2O	0.5 g	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Solvent	DMF	100 mL	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Solvent	ethanol	wash solvent	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP

Partial recipeSource: Both

Route 3: Solvothermal

2 · 2.3 Synthesis of Nd PMOFs

Metal precursorsNd(NO3)3.6H2O

Linker precursorsH2TCPP

Solvents15 mL DMF; sulfuric acid aqueous solution VH2SO4:VH2O = 1:5

Additivessulfuric acid solution

Temperature120

Time12

Work-upDark purple crystal precipitate collected and dried for subsequent use.

ActivationDried; exact temperature/time not specified.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	H2TCPP	0.05 g	2 · 2.3 Synthesis of Nd PMOFs
Metal Source	Nd(NO3)3.6H2O	0.15 g	2 · 2.3 Synthesis of Nd PMOFs
Solvent	DMF	15 mL	2 · 2.3 Synthesis of Nd PMOFs
Acid	sulphuric acid solution	5 mL · VH2SO4:VH2O = 1:5	2 · 2.3 Synthesis of Nd PMOFs

Partial recipeSource: Both

Route 4: Solvothermal

2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs

Metal precursorsNi-TCPP; Nd(NO3)3.6H2O

Linker precursorsNi-TCPP

Solvents10 mL DMF; 5 mL ethanol; sulfuric acid aqueous solution VH2SO4:VH2O = 1:3

Additivessulfuric acid solution

Temperature100

Time12

Work-upRed-purple crystal precipitate collected and dried for further use.

ActivationDried; exact temperature/time not specified.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	Ni-TCPP	0.05 g	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Metal Source	Nd(NO3)3.6H2O	0.1 g	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Solvent	DMF	10 mL	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Acid	sulphuric acid solution	5 mL · VH2SO4:VH2O = 1:3	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs
Solvent	ethanol	5 mL	2 · 2.4 Synthesis of Ni-Nd PMOFs and Co-Nd PMOFs

Complete recipeSource: Both

Route 5: Solvothermal

2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP

Metal precursorsNi(NO3)2.6H2O

Linker precursorsH2TCPP

Solvents50 mL 0.2 mol/L NaOH(aq); 100 mL DMF

AdditivesNaOH

Temperature120

Time24

Work-upPrecipitate collected, washed 3 times with ethanol, dried at 80 C for 12 h.

ActivationDried at 80 C for 12 h.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	H2TCPP	0.5 g	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Base	sodium hydroxide solution	50 mL · 0.2 mol/L	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Metal Source	Ni(NO3)2.6H2O	0.5 g	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Solvent	DMF	100 mL	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP
Solvent	ethanol	wash solvent	2 · 2.2 Synthesis of Ni-TCPP and Co-TCPP