Measurement evidence
Highly conductive three-dimensional metal organic frameworks from small in situ generated ligands · Hazarika U.N., Borah J., Kakoti A. et al. · Materials Advances · 2023 · 6304-6311
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Co-F as-synthesised crystals · Single Crystal
PXRD experimental pattern compared with simulated pattern for phase/crystallinity check
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD phase match | experimental PXRD pattern shown against simulated pattern | — | — | Caption Qualitative | S3 · Supporting Information · Fig. S1 |
Co-F as-synthesised crystals · Single Crystal
Crystal structure solved/refined by SHELXTL/SHELXL; Mo Kalpha radiation in CIF
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Unit-cell a | 8.1984 | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell b | 8.1984 | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell c | 22.256 | — | — | Text Exact Reported | CIF text · CIF |
| C-O bond length | 1.247 | — | — | Text Exact Reported | CIF text · CIF |
| Crystal system | Trigonal | — | — | Text Exact Reported | CIF text · CIF |
| Calculated crystal density | 1.984 | — | — | Text Exact Reported | CIF text · CIF |
| M-O bond length | 2.111 | — | — | Text Exact Reported | CIF text · CIF |
| Space group | R-3c | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell volume | 1295.5 | — | — | Text Exact Reported | CIF text · CIF |
d-Co-F deguested pressed pellet · Pellet
PXRD after thermal guest-removal treatment; Co-F after heating shown in SI
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD after guest removal | framework retained/stability discussed | — | — | Caption Qualitative | S6-S7 · Supporting Information · Fig. S8-S9 |
d-Mn-F deguested pressed pellet · Pellet
PXRD after thermal guest-removal treatment; Mn-F after heating shown in SI
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD after guest removal | structural changes observed at 200 C | — | — | Caption Qualitative | S6-S7 · Supporting Information · Fig. S8-S9 |
d-Ni-F deguested pressed pellet · Pellet
PXRD after thermal guest-removal treatment; Ni-F after heating shown in SI
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD after guest removal | framework retained/stability discussed | — | — | Caption Qualitative | S6-S7 · Supporting Information · Fig. S8-S9 |
Mn-F as-synthesised crystals · Single Crystal
PXRD experimental pattern compared with simulated pattern for phase/crystallinity check
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD phase match | experimental PXRD pattern shown against simulated pattern | — | — | Caption Qualitative | S3 · Supporting Information · Fig. S1 |
Mn-F as-synthesised crystals · Single Crystal
Crystal structure solved/refined by SHELXTL/SHELXL; Mo Kalpha radiation in CIF
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Unit-cell a | 8.384 | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell b | 8.384 | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell c | 23.021 | — | — | Text Exact Reported | CIF text · CIF |
| C-O bond length | 1.251 | — | — | Text Exact Reported | CIF text · CIF |
| Crystal system | Trigonal | — | — | Text Exact Reported | CIF text · CIF |
| Calculated crystal density | 1.897 | — | — | Text Exact Reported | CIF text · CIF |
| M-O bond length | 2.203 | — | — | Text Exact Reported | CIF text · CIF |
| Space group | R-3c | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell volume | 1401.4 | — | — | Text Exact Reported | CIF text · CIF |
Ni-F as-synthesised crystals · Single Crystal
PXRD experimental pattern compared with simulated pattern for phase/crystallinity check
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD phase match | experimental PXRD pattern shown against simulated pattern | — | — | Caption Qualitative | S3 · Supporting Information · Fig. S1 |
Ni-F as-synthesised crystals · Single Crystal
Paper describes Ni-F as isostructural, but no Ni-F CIF or SI crystallographic table row was supplied in the assigned documents.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni-F structural assignment | isostructural trigonal formate MOF, but numeric CIF data not supplied | — | — | Qualitative Qualitative | p002 · Results and discussion · Fig. 1; Fig. 2 |
Zn-F as-synthesised crystals · Single Crystal
PXRD experimental pattern compared with simulated pattern for phase/crystallinity check
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD phase match | experimental PXRD pattern shown against simulated pattern | — | — | Caption Qualitative | S3 · Supporting Information · Fig. S1 |
Zn-F as-synthesised crystals · Single Crystal
Crystal structure solved/refined by SHELXTL/SHELXL; Mo Kalpha radiation in CIF
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Unit-cell a | 8.1966 | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell b | 8.1966 | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell c | 22.28 | — | — | Text Exact Reported | CIF text · CIF |
| C-O bond length | 1.244 | — | — | Text Exact Reported | CIF text · CIF |
| Crystal system | Trigonal | — | — | Text Exact Reported | CIF text · CIF |
| Calculated crystal density | 2.048 | — | — | Text Exact Reported | CIF text · CIF |
| M-O bond length | 2.114 | — | — | Text Exact Reported | CIF text · CIF |
| Space group | R-3c | — | — | Text Exact Reported | CIF text · CIF |
| Unit-cell volume | 1296.32 | — | — | Text Exact Reported | CIF text · CIF |