Spectroscopy — Highly conductive three-dimensional metal organic frameworks from small in situ generated ligands

6 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co-F as-synthesised crystals · Single Crystal

C-O stretching frequency before and after heating reported in SI Table S2; spectra recorded 4000-450 cm^-1 at room temperature

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-O stretching frequency after heating	1585 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2
C-O stretching frequency before heating	1573 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2

Co-F as-synthesised crystals · Single Crystal

Co-F and d-Co-F XPS 2p spectra before and after guest removal

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-F Co 2p1/2 centre peak	796.27 eV	—	—	Text Exact Reported	p005-p006 · Results and discussion · Fig. 7
Co-F Co 2p1/2 shakeup satellite	801.13 eV	—	—	Text Exact Reported	p005-p006 · Results and discussion · Fig. 7
Co-F Co 2p3/2 centre peak	780.46 eV	—	—	Text Exact Reported	p005-p006 · Results and discussion · Fig. 7
Co-F Co 2p3/2 shakeup satellite	784.55 eV	—	—	Text Exact Reported	p005-p006 · Results and discussion · Fig. 7
d-Co-F oxidation-state assignment	contains both Co2+ and Co3+	—	—	Text Qualitative	p006 · Results and discussion · Fig. 7
d-Co-F deconvoluted Co2+ peak	780.94 eV	—	—	Text Exact Reported	p005-p006 · Results and discussion · Fig. 7
d-Co-F deconvoluted Co3+ peak	782.26 eV	—	—	Text Exact Reported	p005-p006 · Results and discussion · Fig. 7

Mn-F as-synthesised crystals · Single Crystal

C-O stretching frequency before and after heating reported in SI Table S2; spectra recorded 4000-450 cm^-1 at room temperature

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-O stretching frequency after heating	1587 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2
C-O stretching frequency before heating	1574 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2

Mn-F as-synthesised crystals · Single Crystal

Mn-F and d-Mn-F XPS 2p spectra before and after guest removal; Thermo Scientific K-Alpha, monochromated micro-focused Mg Kalpha source

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
d-Mn-F XPS change after guest removal	no obvious change in spectra	—	—	Text Qualitative	p005 · Results and discussion · Fig. 7
Mn 2p centre peak	642.28 eV	—	—	Text Exact Reported	p005 · Results and discussion · Fig. 7
Mn 2p satellite peak	645 eV	—	—	Text Rounded Reported	p005 · Results and discussion · Fig. 7

Ni-F as-synthesised crystals · Single Crystal

C-O stretching frequency before and after heating reported in SI Table S2; spectra recorded 4000-450 cm^-1 at room temperature

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-O stretching frequency after heating	1587 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2
C-O stretching frequency before heating	1585 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2

Zn-F as-synthesised crystals · Single Crystal

C-O stretching frequency before and after heating reported in SI Table S2; spectra recorded 4000-450 cm^-1 at room temperature

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-O stretching frequency after heating	1630 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2
C-O stretching frequency before heating	1614 cm^-1	—	—	SI Table Exact Reported	S4 · Supporting Information · Table S2