cMOF Evidence Base

Synthesis evidence

Dielectric relaxation processes, electronic structure, and band gap engineering of MFU-4-type metal-organic frameworks: Towards a rational design of semiconducting microporous materials

Sippel P., Denysenko D., Loidl A. et al. · Advanced Functional Materials · 2014 · 3885-3896

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Main

Route 1: Unknown

p010 · Experimental Section, Synthesis of Framework Compounds

SolventsN,N-dimethylformamide (DMF) present as synthesis solvent/occluded guest
Atmospherevacuum during activation
Temperature280
Time16
Work-upobtained powder particle size 2-10 um; full synthesis referred to previous report
Activationheated 16 h at 280 C under vacuum to remove DMF; dielectric samples evacuated 48 h before measurement
Scalability contextPowder synthesis; no yield or scale reported in this paper.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
SolventN,N-dimethylformamide (DMF)Not specifiedp010 · Experimental Section, Synthesis of Framework Compounds
Vague recipeSource: Main

Route 2: Unknown

p002 · Introduction / Experimental Section

SolventsN,N-dimethylformamide (DMF) initially occluded
Atmospherehigh vacuum / vacuum
Temperature320
Time16
Work-upsame MFU-4 synthesis as prior report; high-temperature activation for solvent-removal comparison
Activationheated to 320 C and kept 16 h in high vacuum; used to remove DMF completely
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
SolventN,N-dimethylformamide (DMF)Not specifiedp002 · Introduction / Experimental Section
Vague recipeSource: Main

Route 3: Unknown

p010 · Experimental Section, Synthesis of Framework Compounds

SolventsN,N-dimethylformamide (DMF) retained
Work-upmeasured as prepared without DMF removal
Activationnone; DMF not removed
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
SolventN,N-dimethylformamide (DMF)Not specifiedp010 · Experimental Section, Synthesis of Framework Compounds
Vague recipeSource: Main

Route 4: Unknown

p010 · Experimental Section, Synthesis of Framework Compounds

SolventsN,N-dimethylformamide (DMF) present as synthesis solvent/occluded guest
Atmospherevacuum during activation
Temperature280
Time16
Work-upobtained powder particle size 2-10 um; full synthesis referred to previous report
Activationheated 16 h at 280 C under vacuum to remove DMF; dielectric samples evacuated 48 h before measurement
Scalability contextPowder synthesis; no yield or scale reported in this paper.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
SolventN,N-dimethylformamide (DMF)Not specifiedp010 · Experimental Section, Synthesis of Framework Compounds