Cao L.-A., Li Y.-Q., Huo Y.-F. et al. · Chinese Journal of Chemistry · 2025 · 371-377
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
A single Cu-HHTP[001] chemiresistor can distinguish FCB from FUB, FTB and BP with 97.2% LDA classification accuracy.
Caveat: LDA calculation method is reported in the SI; raw classification input table is not supplied. humidity response is a caveat.
p004 · Results and Discussion · Figure 4a · Linked to 5 structured results
Humidity substantially decreases the Cu-HHTP[001] sensor response, so anti-humidity interference remains an unresolved limitation.
Caveat: Quantitative humidity response is shown graphically in SI Figure S15; no table values are supplied.
p004 · Results and Discussion · Figure S15 · Linked to 1 structured result
The films are assigned as Cu3(HHTP)2 based on UV-vis growth behaviour, SEM/AFM morphology, TEM/SAED, FT-IR coordination shifts and XPS elemental detection.
Caveat: Several supporting spectra/profiles are available as SI figures, but text gives selected numeric values only.
p002-p003 · Results and Discussion · Figure 2; Figures S1, S4-S6 · Linked to 5 structured results
Orientation-controlled Cu3(HHTP)2 thin films show anisotropic sensing: Cu-HHTP[001] has a higher FCB response and faster response/recovery than Cu-HHTP[100].
Caveat: Absolute baseline current/conductivity values are not reported; absolute conductivity values are not reported.
p003-p004 · Results and Discussion · Figure 3a-b · Linked to 6 structured results
FCB volatile components donate electrons to p-type Cu3(HHTP)2, shifting the Fermi level upward and increasing resistance.
Caveat: The authors state the exact mechanism is still to be revealed; UPS supports but does not fully prove the mechanism.
p005 · Results and Discussion · Figure 4b · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu-HHTP[001] oriented Cu3(HHTP)2 thin filmBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2Cu2+ ions coordinated to HHTP ligands · HHTP | 2D · PristineAnisotropic Cu3(HHTP)2 thin film grown along the [001] orientation by layer-by-layer immersion in ethanolic Cu(OAc)2 and HHTP solutions. | p002 · Results and Discussion · Figure 1 |
| Cu-HHTP[100] oriented Cu3(HHTP)2 thin filmBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2Cu2+ ions coordinated to HHTP ligands · HHTP | 2D · PristineAnisotropic Cu3(HHTP)2 thin film grown along the [100] orientation by layer-by-layer immersion in aqueous Cu(OAc)2 and HHTP solutions. | p002 · Results and Discussion · Figure 1 |
| Cu3(HHTP)2 conductive metal-organic frameworkBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu2+ ions coordinated to HHTP ligands · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineHexagonal 2D honeycomb layered conductive MOF; HR-TEM lattice fringe assigned to the [100] crystal plane. | p003 · Results and Discussion · Figure 2g-i |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Cu-HHTP[001]-20C thin filmresearch_0759__mat__cu_hhtp_001 | Thin Film · Target Sample · Pristine Framework | 20 growth-cycle [001]-oriented Cu3(HHTP)2 film selected for characterisation and gas-sensing tests.not fully specified in main text · 70 nm | p002 · Results and Discussion · Figure 2c,e; Figure S1 |
| Cu-HHTP[001]-10C/20C/30C/40C film seriesresearch_0759__mat__cu_hhtp_001 | Thin Film · Target Sample · Pristine Framework | Layer-by-layer grown [001]-oriented pristine Cu3(HHTP)2 films.quartz glass for UV-vis; alumina substrate for devices where fabricated as chemiresistors · controlled by growth cycles; 10C, 20C, 30C, 40C | p002 · Results and Discussion · Figure 2a |
| FCB-related volatolomics adsorbed Cu-HHTP[001] filmresearch_0759__mat__cu_hhtp_001 | Thin Film · Target Sample · Guest Loaded | Cu-HHTP[001] film after adsorption of FCB-related volatile components for UPS comparison.not specified for UPS specimen · active film about 70 nm for the corresponding 20C film | p004-p005 · Results and Discussion · Figure 4b |
| Cu-HHTP[001] chemiresistor deviceresearch_0759__mat__cu_hhtp_001 | Electrode · Target Sample · Composite | Cu-HHTP[001] film on alumina with silver wires fixed by conductive silver paste at both electrode ends.alumina substrate, 13.4 mm x 7 mm x 0.635 mm · active film about 70 nm | p005 · Chemiresistive gas sensing measurements · Figure S13 |
| Cu-HHTP[100]-20C thin filmresearch_0759__mat__cu_hhtp_100 | Thin Film · Target Sample · Pristine Framework | 20 growth-cycle [100]-oriented Cu3(HHTP)2 film selected for characterisation and gas-sensing tests.not fully specified in main text · 110 nm | p002 · Results and Discussion · Figure 2d,f; Figure S1 |
| Cu-HHTP[100]-10C/20C/30C/40C film seriesresearch_0759__mat__cu_hhtp_100 | Thin Film · Target Sample · Pristine Framework | Layer-by-layer grown [100]-oriented pristine Cu3(HHTP)2 films.quartz glass for UV-vis; alumina substrate for devices where fabricated as chemiresistors · controlled by growth cycles; 10C, 20C, 30C, 40C | p002 · Results and Discussion · Figure 2b |
| Cu-HHTP[100] chemiresistor deviceresearch_0759__mat__cu_hhtp_100 | Electrode · Target Sample · Composite | Cu-HHTP[100] film on alumina with silver wires fixed by conductive silver paste at both electrode ends.alumina substrate, 13.4 mm x 7 mm x 0.635 mm · active film about 110 nm | p005 · Chemiresistive gas sensing measurements · Figure S13 |