Microscopy Morphology — Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance

3 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co-DHHBTN powder · Powder

SEM at 5 kV; EDX at 15 kV; TEM at 200 kV after drop-casting ethanol suspension onto copper grid.

Atmosphere: 10^-6 torr for SEM/EDX
Context: powder pristine
Measurement source: 4 · Structural Characterizations · Figure 3; Figures S9-S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Elemental analysis found C	52.2%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
Elemental analysis found H	4.5%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
Elemental analysis found Co	10.9%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
HRTEM fringe distance (100)	2.44 nm	—	—	Text Exact Reported	4 · Structural Characterizations · Figure S13a
TGA weight loss	20.6% at 473 K	—	—	Text Exact Reported	4 · Structural Characterizations · Figure S18
SEM morphology	rod-shaped crystallites with lengths from hundreds of nanometers to several micrometers and widths up to hundreds of nanometers	—	—	Text Qualitative	4 · Structural Characterizations · Figure 3; Figure S9

Cu-DHHBTN powder · Powder

SEM at 5 kV; EDX at 15 kV; TEM at 200 kV after drop-casting ethanol suspension onto copper grid.

Atmosphere: 10^-6 torr for SEM/EDX
Context: powder pristine
Measurement source: 4 · Structural Characterizations · Figure 3; Figures S9-S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Elemental analysis found C	47.9%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
Elemental analysis found H	3.9%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
Elemental analysis found Cu	13.8%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
HRTEM stacking assignment	slipped parallel packing mode	—	—	Text Qualitative	4 · Structural Characterizations · Figure 3e; Figure S13c
TGA weight loss	13.7% at 393 K	—	—	Text Exact Reported	4 · Structural Characterizations · Figure S18

Ni-DHHBTN powder · Powder

SEM at 5 kV; EDX at 15 kV; TEM at 200 kV after drop-casting ethanol suspension onto copper grid.

Atmosphere: 10^-6 torr for SEM/EDX
Context: powder pristine
Measurement source: 4 · Structural Characterizations · Figure 3; Figures S9-S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Elemental analysis found C	46.1%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
Elemental analysis found H	4.7%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
Elemental analysis found Ni	11.3%	—	—	SI Table Exact Reported	S16 · Elemental Analysis · Table S1
HRTEM fringe distance (100)	2.46 nm	—	—	Text Exact Reported	4 · Structural Characterizations · Figure 3d; Figure S13b
TGA weight loss	18.2% at 473 K	—	—	Text Exact Reported	4 · Structural Characterizations · Figure S18