cMOF Evidence Base

Synthesis evidence

Correlation in Structural Architecture toward Fabrication of Schottky Device with a Series of Pyrazine Appended Coordination Polymers

Bhunia S., Sahoo D., Dutta B. et al. · Inorganic Chemistry · 2023 · 20948-20960

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

20949 · Device Fabrication

SolventsDMSO dispersion; acetone, soap solution, distilled water and ethanol for cleaning
Atmospherenot specified
Temperaturenot specified
Substrate orientationITO-coated glass
Work-upSpin coating at 1000 rpm for 60 s, drying, Al thermal evaporation; diode area 3 x 3 mm2.
Scalability contextThin-film device fabrication reported; dispersion concentration not specified.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
SolventDMSOnot stated20949 · Device Fabrication
OtherAl rectifier contactthermal evaporation process20949 · Device Fabrication
Complete recipeSource: Both

Route 2: Liquid Liquid Interface

20949 · Synthesis and Formulation · Scheme S1

Metal precursorsCd(NO3)2.4H2O
Linker precursorstppz; H2adc
Solventswater; methanol; water-methanol 1:1 v/v; ethanol
AdditivesEt3N
Atmospherenot specified
Temperaturenot specified
Time120
Work-upUnstirred layered solution gave colourless block crystals within 5 days.
ActivationNone reported for synthesis; activated samples mentioned only for N2 sorption.
Scalability contextSmall single-crystal layering synthesis; no scale-up data.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCd(NO3)2.4H2O0.06 g, 0.2 mmol20949 · Synthesis and Formulation · Scheme S1
Linkertppz0.0194 g, 0.05 mmol20949 · Synthesis and Formulation · Scheme S1
AcidH2adc0.023 g, 0.2 mmol20949 · Synthesis and Formulation · Scheme S1
BaseEt3N0.042 g, 0.4 mmol20949 · Synthesis and Formulation · Scheme S1
Solventwater/methanol/ethanolaqueous 2 mL; water-methanol 2 mL; methanol 2 mL; ethanol 2 mL20949 · Synthesis and Formulation · Scheme S1
Partial recipeSource: Main

Route 3: Other

20949 · Device Fabrication

SolventsDMSO dispersion; acetone, soap solution, distilled water and ethanol for cleaning
Atmospherenot specified
Temperaturenot specified
Substrate orientationITO-coated glass
Work-upSpin coating at 1000 rpm for 60 s, drying, Al thermal evaporation; diode area 3 x 3 mm2.
Scalability contextThin-film device fabrication reported; dispersion concentration not specified.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
SolventDMSOnot stated20949 · Device Fabrication
OtherAl rectifier contactthermal evaporation process20949 · Device Fabrication
Partial recipeSource: Both

Route 4: Liquid Liquid Interface

20949 · Synthesis and Formulation · Scheme S1

Metal precursorsCd(NO3)2.4H2O
Linker precursorstppz; H2trep
Solventswater; methanol; water-methanol 1:1 v/v; ethanol inferred from similar procedure
AdditivesEt3N inferred from similar procedure
Atmospherenot specified
Temperaturenot specified
Timeabout 168
Work-upColourless crystals obtained within a week.
ActivationNone reported for synthesis; activated samples mentioned only for N2 sorption.
Scalability contextSmall single-crystal layering synthesis; no scale-up data.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCd(NO3)2.4H2Osame as model synthesis inferred; exact repeated amount not stated for 220949 · Synthesis and Formulation · Scheme S1
Linkertppzsame as model synthesis inferred; exact repeated amount not stated for 220949 · Synthesis and Formulation · Scheme S1
AcidH2trepnot stated20949 · Synthesis and Formulation · Scheme S1
Partial recipeSource: Main

Route 5: Other

20949 · Device Fabrication

SolventsDMSO dispersion; acetone, soap solution, distilled water and ethanol for cleaning
Atmospherenot specified
Temperaturenot specified
Substrate orientationITO-coated glass
Work-upSpin coating at 1000 rpm for 60 s, drying, Al thermal evaporation; diode area 3 x 3 mm2.
Scalability contextThin-film device fabrication reported; dispersion concentration not specified.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
SolventDMSOnot stated20949 · Device Fabrication
OtherAl rectifier contactthermal evaporation process20949 · Device Fabrication
Partial recipeSource: Both

Route 6: Liquid Liquid Interface

20949 · Synthesis and Formulation · Scheme S1

Metal precursorsCd(NO3)2.4H2O
Linker precursorstppz; 2,6 H2ndc
Solventswater; methanol; water-methanol 1:1 v/v; ethanol inferred from similar procedure
AdditivesEt3N inferred from similar procedure
Atmospherenot specified
Temperaturenot specified
Timeabout 168
Work-upColourless crystals obtained within a week.
ActivationNone reported for synthesis; activated samples mentioned only for N2 sorption.
Scalability contextSmall single-crystal layering synthesis; no scale-up data.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCd(NO3)2.4H2Osame as model synthesis inferred; exact repeated amount not stated for 320949 · Synthesis and Formulation · Scheme S1
Linkertppzsame as model synthesis inferred; exact repeated amount not stated for 320949 · Synthesis and Formulation · Scheme S1
Acid2,6 H2ndcnot stated20949 · Synthesis and Formulation · Scheme S1