cMOF Evidence Base
Electrical Transport — Operando Raman and ex situ characterization of an iron-based conductive MOF as a negative electrode in Li-ion batteries

Measurement evidence

Electrical Transport

Operando Raman and ex situ characterization of an iron-based conductive MOF as a negative electrode in Li-ion batteries · Ciria-Ramos I., Neale A.R., Hardwick L.J. et al. · Dalton Transactions · 2025 · 9714-9725

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Two-point probe electronic conductivity from EIS-fitted resistance

Electrical conductivityImpedance spectroscopy

Fe-HHTP powder pellet in Swagelok two-probe cell · Pellet

Fe-HHTP powder between stainless steel current collectors of Swagelok cell; EIS 1e6 to 1e-2 Hz; 1 V applied; 226 MPa pressure; Randles equivalent circuit; sigma = l/(R*A).

Geometry
two stainless steel current collectors, 7 mm diameter, pressed pellet
Context
pristine Fe-HHTP powder pellet
Measurement source
10 · 4.2 Powder and electrodes ex situ characterization techniques · Figure S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Bulk electronic conductivityMarked as a best value within this paper5.40 x 10^-4 S m^-10.00054 S m-1—Text
Exact Reported		3 · 2.1 MOF powder characterization · Figure S6
Pressure during conductivity measurement226 MPa——Text
Exact Reported		10 · 4.2 Powder and electrodes ex situ characterization techniques · Figure S6