Spectroscopy — Strategies to enhance electrochemical performance of isoreticular 2d conjugated metal correlated organic frameworks via transition metals intercalation for battery-supercapacitor hybrids

4 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

As-synthesised Cu-MOF crystals/powder · Powder

FTIR band assignments for CH, CO, CC aromatic bending, OH stretching, and metal-linker/water bonding.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR CC aromatic ring bending band range	1450-1600 cm-1 assigned to CC modes of aromatic ring bending.	—	—	Text Range	4 · 3.1. Structural and morphological study · Fig. 2g
FTIR OH stretching band range	3100-3250 cm-1 assigned to OH stretching.	—	—	Text Range	4 · 3.1. Structural and morphological study · Fig. 2g

As-synthesised Ni-MOF crystals/powder · Powder

FTIR band assignments for CH, CO, CC aromatic bending, OH stretching, and metal-linker/water bonding.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR CH bending band range	650-850 cm-1 assigned to CH mode / aromatic ring bending region.	—	—	Text Range	4 · 3.1. Structural and morphological study · Fig. 2g
FTIR CO band range	1200-1350 cm-1 assigned to CO mode.	—	—	Text Range	4 · 3.1. Structural and morphological study · Fig. 2g
FTIR metal-linker/water bond peak	657 cm-1 peak assigned to bond formation between metal ions and HHTP linkers and between metal ions and water molecules.	—	—	Text Rounded Reported	4 · 3.1. Structural and morphological study · Fig. 2g

As-synthesised Cu-MOF crystals/powder · Powder

Raman spectrum used to identify G band from sp2 hybridised carbon in triphenylene units.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-MOF Raman G band assignment	G band indicates sp2 hybridised carbon atoms in triphenylene building blocks.	—	—	Text Qualitative	4 · 3.1. Structural and morphological study · Fig. 2d

As-synthesised Ni-MOF crystals/powder · Powder

Raman spectrum used to identify G band from sp2 hybridised carbon in triphenylene units.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-MOF Raman G band assignment	G band indicates sp2 hybridised carbon atoms in triphenylene building blocks.	—	—	Text Qualitative	4 · 3.1. Structural and morphological study · Fig. 2d