cMOF Evidence Base

Synthesis evidence

Strategies to enhance electrochemical performance of isoreticular 2d conjugated metal correlated organic frameworks via transition metals intercalation for battery-supercapacitor hybrids

Iqbal M.Z., Shaheen M., Siddique S. et al. · Journal of Energy Storage · 2023 · 107361

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Other

Section 1.1 Charge balance

Metal precursorsCu-MOF slurry electrode
AdditivesActivated carbon counter electrode; KOH electrolyte
Atmospherenot reported
Substrate orientationTwo-electrode asymmetric device
Work-upMass balance equation used; Cu-MOF:AC deposited mass ratio 0.5:1.
Activationnot reported
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherCu-MOF electrodeCu-MOF:AC deposited mass ratio 0.5:1Section 1.1 Charge balance
Otheractivated carbon electrodeCu-MOF:AC deposited mass ratio 0.5:1Section 1.1 Charge balance
ElectrolyteKOH3 M used for electrochemical measurementsSection 1.1 Charge balance
Vague recipeSource: Main

Route 2: Drop Cast

3 · 2.3. Structural and electrochemical characterizations

Metal precursorsAs-synthesised Cu-MOF
SolventsN-methyl-2-pyrrolidone (NMP)
AdditivesAcetylene black; PVDF binder
Atmospherenot reported
Substrate orientationNickel foam, 1 x 1 cm2 area
Work-upSlurry deposited on nickel foam; drying conditions not reported.
Activationnot reported
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherCu-MOF4 mg mass loading for three cell measurement3 · 2.3. Structural and electrochemical characterizations
Additiveacetylene blackNot specified3 · 2.3. Structural and electrochemical characterizations
Additivepolyvinylidene fluoride (PVDF) binderNot specified3 · 2.3. Structural and electrochemical characterizations
SolventN-methyl-2-pyrrolidone (NMP)Not specified3 · 2.3. Structural and electrochemical characterizations
Partial recipeSource: Main

Route 3: Other

2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1

Metal precursorsCopper trifluroacetylacetonate (10 mg)
Linker precursorsHHTP linker (7 mg)
Solvents4 ml deionized water
Atmospherenot reported
Temperature85
Time12
Work-upWashed through centrifugation using DI water and acetone; left for drying.
Activationnot reported
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcecopper trifluroacetylacetonate10 mg2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1
Linker2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)7 mg2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1
Solventdeionized (DI) water4 ml2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1
Partial recipeSource: Both

Route 4: Other

Section 1.1 Charge balance

Metal precursorsNi-MOF slurry electrode
AdditivesActivated carbon counter electrode; KOH electrolyte
Atmospherenot reported
Substrate orientationTwo-electrode asymmetric device
Work-upMass balance equation used; Ni-MOF:AC deposited mass ratio 1:2.2.
Activationnot reported
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherNi-MOF electrodeNi-MOF:AC deposited mass ratio 1:2.2Section 1.1 Charge balance
Otheractivated carbon electrodeNi-MOF:AC deposited mass ratio 1:2.2Section 1.1 Charge balance
ElectrolyteKOH3 M used for electrochemical measurementsSection 1.1 Charge balance
Vague recipeSource: Main

Route 5: Drop Cast

3 · 2.3. Structural and electrochemical characterizations

Metal precursorsAs-synthesised Ni-MOF
SolventsN-methyl-2-pyrrolidone (NMP)
AdditivesAcetylene black; PVDF binder
Atmospherenot reported
Substrate orientationNickel foam, 1 x 1 cm2 area
Work-upSlurry deposited on nickel foam; drying conditions not reported.
Activationnot reported
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherNi-MOF4 mg mass loading for three cell measurement3 · 2.3. Structural and electrochemical characterizations
Additiveacetylene blackNot specified3 · 2.3. Structural and electrochemical characterizations
Additivepolyvinylidene fluoride (PVDF) binderNot specified3 · 2.3. Structural and electrochemical characterizations
SolventN-methyl-2-pyrrolidone (NMP)Not specified3 · 2.3. Structural and electrochemical characterizations
Partial recipeSource: Main

Route 6: Other

2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1

Metal precursorsNickel acetate tetrahydrate (10 mg)
Linker precursorsHHTP linker (7 mg)
Solvents4 ml deionized water
Atmospherenot reported
Temperature85
Time12
Work-upWashed through centrifugation using DI water and acetone; left for drying.
Activationnot reported
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcenickel acetate tetrahydrate10 mg2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1
Linker2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)7 mg2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1
Solventdeionized (DI) water4 ml2 · 2.2. Synthesis of Ni-MOF, Cu-MOF and activated carbon (AC) · Fig. 1