Fan K., Fu C., Chen Y. et al. · Advanced Science · 2023 · 2205760
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The 1D-CuTABQ conductivity is reported as 9.7 x 10^-3 S m^-1 in the main text but 9.3 x 10^-3 S/m in the SI Figure S11 caption.
Caveat: Both values are retained rather than corrected.
5 · 2.1 Synthesis and Characterization · Figures S11-S12 · Linked to 2 structured results
The porous 2D framework improves dual-ion storage, rate capability and long-cycle stability relative to 1D-CuTABQ despite lower bulk pellet conductivity.
Caveat: Electrochemical electrodes are composites with carbon and PVDF, so device performance is not a pristine-powder transport measurement.
6,8 · 2.2 Electrochemical Performance; 2.4 Reaction Kinetics · Figure 4; Figures S33-S39 · Linked to 6 structured results
Changing reaction atmosphere, base availability, temperature and confinement directs the same Cu/TABQ chemistry to 1D square-planar CuTABQ or 2D octahedral mixed-valence CuTABQ.
Caveat: Valence assignments are inferred from spectroscopy and elemental ratios, not single-crystal structures.
4,8 · 2.1 Synthesis and Characterization; Conclusion · Figure 1 · Linked to 4 structured results
Charge storage involves ligand C=O/C-O redox with Na+ insertion/extraction, Cu2+/Cu+ redox, and PF6- anion storage at high voltage; the anion process is stronger in 2D-CuTABQ.
Caveat: Some mechanistic assignments are ex situ and may not capture transient states.
7-8 · 2.3 Charge-Storage Mechanism · Figure 5 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| 1D-CuTABQ | Cu(C6H4N4O2)(DMSO)0.025(H2O); PXRD ideal formula Cu(C6H4N4O2)Cu ions, predominantly Cu2+ in square-planar Cu-(NH)4 units · 2,3,5,6-tetraaminobenzoquinone (TABQ), inferred as TABQ2- after deprotonation/oxidation | 1D · PristineSquare-planar Cu-(NH)4 chain framework; triclinic P1; slipped pi-stacking between chains and NH...O hydrogen bonding. | 3-4 · 2.1 Synthesis and Characterization · Figure 2; Table S2 cited |
| 2D-CuTABQ | Cu(C6H4N4O2)1.5(DMSO)0.5(H2O); PXRD ideal formula Cu2(C6H4N4O2)3Mixed-valence Cu+/Cu2+ ions in octahedral CuN6 tris-chelating clusters · 2,3,5,6-tetraaminobenzoquinone (TABQ), inferred as oxidised TABQ1- in pristine framework | 2D · PristineTrigonal P-31m 2D (6,3) topology; eclipsed layers form honeycomb-like channels; neutral framework. | 4-5 · 2.1 Synthesis and Characterization · Figure 2; Table S2 cited |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| 1D-CuTABQ composite cathode electroderesearch_0791__mat__mat_1d_cutabq | Electrode · Composite Sample · Composite | active material dried at 120 deg C under vacuum for 12 h; slurry doctor-bladed onto Al foil and dried 12 h at 80 deg C under vacuumAl foil | 3-4 · Electrochemical Measurements |
| DFT model of 1D-CuTABQresearch_0791__mat__mat_1d_cutabq | Model · Model System · Model | periodic DFT-optimised structure | 3 · Computational method |
| pressed-pellet 1D-CuTABQresearch_0791__mat__mat_1d_cutabq | Pellet · Target Sample · Pristine Framework | pressed pellet for linear I-V bulk conductivityL = 0.031 cm | 13 · Figure captions · Figure S11 |
| as-synthesised 1D-CuTABQ powderresearch_0791__mat__mat_1d_cutabq | Powder · Target Sample · Pristine Framework | filtered precipitate washed with DMSO and acetone, then dried at 80 deg C | 2 · Experimental section · Synthesis of 1D-CuTABQ |
| 2D-CuTABQ composite cathode electroderesearch_0791__mat__mat_2d_cutabq | Electrode · Composite Sample · Composite | active material dried at 120 deg C under vacuum for 12 h; slurry doctor-bladed onto Al foil and dried 12 h at 80 deg C under vacuumAl foil | 3-4 · Electrochemical Measurements |
| DFT model of 2D-CuTABQresearch_0791__mat__mat_2d_cutabq | Model · Model System · Model | periodic DFT-optimised 2D (6,3) topology | 11 · Figure captions · Figure S9 |
| pressed-pellet 2D-CuTABQresearch_0791__mat__mat_2d_cutabq | Pellet · Target Sample · Pristine Framework | pressed pellet for linear I-V bulk conductivityL = 0.038 cm | 13 · Figure captions · Figure S12 |
| as-synthesised 2D-CuTABQ powderresearch_0791__mat__mat_2d_cutabq | Powder · Target Sample · Pristine Framework | black precipitate collected by vacuum filtration and washed with water | 2 · Experimental section · Synthesis of 2D-CuTABQ |