Complete recipeSource: Both
Route 1: Other
2 · Experimental section · Synthesis of 1D-CuTABQ
Metal precursorsCu(NO3)2.3H2O (241.5 mg, 1 mmol)
Linker precursorsfresh 2,3,5,6-tetraaminobenzoquinone (TABQ, 168 mg, 1 mmol)
SolventsDMSO, 30 mL for Cu salt and 30 mL for TABQ
Additivesconcentrated aqueous ammonium hydroxide, 3 mL, approx. 14 M
Atmosphereair atmosphere (main text states air and base are required)
Temperatureroom temperature; dried at 80 deg C
Time12 h stirring at 500 rpm; post-synthesis drying time not specified
Oxidant / reductantoxygen from air acts as oxidant during ligand deprotonation/oxidation
Work-upprecipitate isolated by filtration; washed with DMSO (50 mL x 2) and acetone (25 mL x 2); dried in 80 deg C oven
Activationnone beyond oven drying for characterisation
Scalability contextBatch solution precipitation with 244 mg reported yield.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cu(NO3)2.3H2O | 241.5 mg, 1 mmol | 2 · Experimental section · Synthesis of 1D-CuTABQ |
| Linker | 2,3,5,6-tetraaminobenzoquinone (TABQ) | 168 mg, 1 mmol | 2 · Experimental section · Synthesis of 1D-CuTABQ |
| Solvent | DMSO | 30 mL + 30 mL | 2 · Experimental section · Synthesis of 1D-CuTABQ |
| Base | concentrated aqueous ammonium hydroxide | 3 mL · ~14 M | 2 · Experimental section · Synthesis of 1D-CuTABQ |
| Oxidant | air/oxygen | ambient | 2 · Experimental section · Synthesis of 1D-CuTABQ |