Porosity — Macrocycle-Based Metal-Organic Frameworks with NO2-Driven On/Off Switch of Conductivity

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

MOF A-100 heated/dehydrated crystals · Single Crystal

CO2 adsorption/desorption isotherm at 273 K; BET surface area and pore diameter reported.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of MOF A-100Marked as a best value within this paper	about 104 m2/g	104000 m^2/kg	about	Text Approximate	main p.5 · Results and Discussion · Figure S24
CO2 adsorption capacity of MOF A-100	38 cm3/g at 273 K	—	—	Text Rounded Reported	main p.5 · Results and Discussion · Figure S24
Pore diameter of MOF A-100	about 0.5 nm	5 angstrom	about	Text Approximate	main p.5 · Results and Discussion · Figure S24

As-grown red MOF A single crystals/powder · Single Crystal

MOF A placed in NO2 environment for 12 h at 298 K and 1 bar context; bottle and sample masses recorded before/after.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NO2 adsorption capacity of MOF A	4.9 mmol/g	4.9 mol/kg	—	Text Rounded Reported	main p.6 · Results and Discussion · Figure 7a
NO2 mass adsorbed by MOF A	47.1 mg NO2 adsorbed by 208.4 mg MOF A	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 7a

MOF A-100 heated/dehydrated crystals · Single Crystal

MOF A-100 placed in NO2 environment for 12 h at 298 K and 1 bar context; bottle and sample masses recorded before/after.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NO2 adsorption capacity of MOF A-100Marked as a best value within this paper	6.5 mmol/g	6.5 mol/kg	—	Text Rounded Reported	main p.6 · Results and Discussion · Figure 7b
NO2 mass adsorbed by MOF A-100	115.8 mg NO2 adsorbed by 384.8 mg MOF A-100	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 7b