Electrochemistry Application — Exposing {001} Crystal Plane on Hexagonal Ni-MOF with Surface-Grown Cross-Linked Mesh-Structures for Electrochemical Energy Storage

Measurement evidence

Electrochemistry Application

Exposing {001} Crystal Plane on Hexagonal Ni-MOF with Surface-Grown Cross-Linked Mesh-Structures for Electrochemical Energy Storage · Li Y., Xu Y., Liu Y. et al. · Small · 2019 · 1902463

10 measurement groups · 31 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

galvanostatic charge-discharge

bare Ni-foam electrode · Electrode

Bare Ni foam in three-electrode cell with 3.0 M KOH; 0.49 V voltage window.

Temperature
room temperature
Geometry
bare nickel foam electrode
Context
control substrate
Measurement source
3 · Results and Discussion · Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
bare Ni foam specific capacitance at 0.5 A g-115.23 F g-1Text
Exact Reported
3 · Results and Discussion · Figure S7

cyclic voltammetry

Y1-Y5//AC aqueous devices · Electrode

Ni-MOF//AC aqueous devices in 3.0 M KOH; voltage window screening and scan rates 5-100 mV s-1.

Temperature
room temperature
Geometry
two-electrode aqueous device
Context
application composite device
Measurement source
6 · Results and Discussion · Figure 4a; Figures S16-S18
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource

cycling stability

Y1-Y5//AC aqueous devices · Electrode

Ni-MOF//AC aqueous devices cycled at 0.5 A g-1.

Temperature
room temperature
Geometry
two-electrode aqueous device
Context
application composite device
Measurement source
6 · Results and Discussion · Figure 4e
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Y3//AC capacitance after 5000 cycles164.20 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4e
Y3//AC capacitance retention after 5000 cyclesMarked as a best value within this paper86.77%Text
Exact Reported
6 · Results and Discussion · Figure 4e

electrochemical impedance spectroscopy

Y1-Y5//AC aqueous devices · Electrode

Device EIS at open-circuit voltage; room temperature.

Temperature
room temperature
Geometry
two-electrode aqueous device
Context
application composite device
Measurement source
6 · Results and Discussion · Figure S20
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
charge transfer resistance comparisonMarked as a best value within this paperY3 is the smallestQualitative
Qualitative
6 · Results and Discussion · Figure S20

galvanostatic charge-discharge

Y1-Y5//AC aqueous devices · Electrode

Ni-MOF//AC aqueous devices in 3.0 M KOH; Y1-Y5 at 0.5 A g-1 and Y3//AC at 0.5, 0.6, 1, 2, 3, and 5 A g-1.

Temperature
room temperature
Geometry
two-electrode aqueous device
Context
application composite device
Measurement source
6 · Results and Discussion · Figure 4b-d; Figure S19
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Y1//AC device specific capacitance at 0.5 A g-1131.25 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4b
Y2//AC device specific capacitance at 0.5 A g-1170.36 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4b
Y3//AC device specific capacitance at 0.5 A g-1Marked as a best value within this paper189.23 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4b
Y3//AC device specific capacitance at 0.6 A g-1167.08 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4d
Y3//AC device specific capacitance at 1 A g-1149.14 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4d
Y3//AC device specific capacitance at 2 A g-1132.76 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4d
Y3//AC device specific capacitance at 3 A g-1124.14 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4d
Y3//AC device specific capacitance at 5 A g-1116.38 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4d
Y4//AC device specific capacitance at 0.5 A g-1119.62 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4b
Y5//AC device specific capacitance at 0.5 A g-167.92 F g-1Text
Exact Reported
6 · Results and Discussion · Figure 4b

Ragone plot from GCD curves

Y1-Y5//AC aqueous devices · Electrode

Energy and power densities calculated for Ni-MOF//AC aqueous devices from two-electrode GCD curves.

Temperature
room temperature
Geometry
two-electrode aqueous device
Context
application composite device
Measurement source
7 · Results and Discussion · Figure 4f; Figure S21
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Y3//AC energy density at 3624.87 W kg-133.98 Wh kg-1 under 3624.87 W kg-1Text
Exact Reported
7 · Results and Discussion · Figure 4f
Y3//AC energy density at 362.50 W kg-1Marked as a best value within this paper55.26 Wh kg-1 at 362.50 W kg-1Text
Exact Reported
7 · Results and Discussion · Figure 4f
Y3//AC power density at maximum reported energy density362.50 W kg-1Text
Exact Reported
7 · Results and Discussion · Figure 4f
Y3//AC high power density point3624.87 W kg-1Text
Exact Reported
7 · Results and Discussion · Figure 4f

electrochemical impedance spectroscopy

Y1-Y5 three-electrode working electrodes · Electrode

Three-electrode EIS in 3.0 M KOH from 100 kHz to 0.01 Hz at open-circuit voltage.

Temperature
room temperature
Geometry
Ni-MOF/acetylene black/PTFE working electrode on nickel foam
Context
composite working electrode made from pristine Ni-MOF
Measurement source
5 · 1.4 Electrochemical measurements · Figure S15
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
relative ion diffusion resistanceMarked as a best value within this paperY3 electrode has lower ion diffusion resistance and superior electrochemical performanceQualitative
Qualitative
5 · Results and Discussion · Figure S15

cyclic voltammetry

Y1-Y5 three-electrode working electrodes · Electrode

Three-electrode cell in 3.0 M KOH; Pt counter; Hg/HgO reference; scan rates 5-100 mV s-1 for Y3 and Y1/Y2/Y4/Y5; potential-window screening at 20 mV s-1.

Temperature
room temperature
Geometry
working electrode on nickel foam, approx. 1 cm2; active material loading approx. 1.0 mg
Context
composite electrode containing pristine Ni-MOF plus conductive carbon/PTFE
Measurement source
4 · Results and Discussion · Figure 3a; Figures S8-S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource

cycling stability

Y1-Y5 three-electrode working electrodes · Electrode

Three-electrode cycling of Y1-Y5 at 0.5 A g-1 in 3.0 M KOH.

Temperature
room temperature
Geometry
Ni-MOF/acetylene black/PTFE working electrode on nickel foam
Context
composite working electrode made from pristine Ni-MOF
Measurement source
4 · Results and Discussion · Figure 3e
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Y3 capacitance retention after 2000 cycles93.55%Text
Exact Reported
4 · Results and Discussion · Figure 3e
Y3 capacitance retention after 5000 cyclesMarked as a best value within this paper92.34%Text
Exact Reported
4 · Results and Discussion · Figure 3e

galvanostatic charge-discharge

Y1-Y5 three-electrode working electrodes · Electrode

Three-electrode cell in 3.0 M KOH; Y1-Y5 at 0.5 A g-1 and Y3 at 0.5, 0.6, 1, 2, 3, and 5 A g-1.

Temperature
room temperature
Geometry
Ni-MOF/acetylene black/PTFE working electrode on nickel foam
Context
composite working electrode made from pristine Ni-MOF
Measurement source
4 · Results and Discussion · Figure 3b-d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Y1 specific capacitance at 0.5 A g-1582.93 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3b
Y2 specific capacitance at 0.5 A g-1945.65 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3b
Y3 specific capacitance at 0.5 A g-1Marked as a best value within this paper977.04 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3b
Y3 specific capacitance at 0.6 A g-1887.75 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3d
Y3 specific capacitance at 1 A g-1788.26 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3d
Y3 specific capacitance at 2 A g-1709.19 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3d
Y3 specific capacitance at 3 A g-1673.48 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3d
Y3 specific capacitance at 5 A g-1612.25 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3d
Y4 specific capacitance at 0.5 A g-1825.80 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3b
Y5 specific capacitance at 0.5 A g-1542.98 F g-1Text
Exact Reported
4 · Results and Discussion · Figure 3b