Electrochemistry Application — Cu-Based Conductive MOF Grown in situ on Cu Foam as a Highly Selective and Stable Non-Enzymatic Glucose Sensor

Measurement evidence

Electrochemistry Application

Cu-Based Conductive MOF Grown in situ on Cu Foam as a Highly Selective and Stable Non-Enzymatic Glucose Sensor · Hu Q., Qin J., Wang X.-F. et al. · Frontiers in Chemistry · 2021 · 786970

4 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry

Cu-MOF/CF electrode · Electrode

Three-electrode test in 0.1 M NaOH with and without 1 mM glucose, scan rate 50 mV s-1, potential range 0-1 V; compared against bare CF.

Temperature
room temperature
Geometry
CHI 660E workstation; Pt counter electrode; Hg/HgO reference electrode; working electrode area 0.2 x 0.2 cm-2
Context
Cu-MOF/CF target electrode with bare CF control
Measurement source
4 · Electrochemical Characterizations · Figure 3A
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
bare CF glucose catalysisbare CF showed no visible redox peak in absence or presence of glucoseText
Qualitative
4 · Electrochemical Characterizations · Figure 3A
Cu-MOF/CF redox activityreversible oxidation and reduction wave; oxidation current enhanced by 1 mM glucoseText
Qualitative
4 · Electrochemical Characterizations · Figure 3A

glucose-concentration-dependent cyclic voltammetry

Cu-MOF/CF electrode · Electrode

Cu-MOF/CF in 0.1 M NaOH with 0-6 mM glucose at 50 mV s-1.

Temperature
room temperature
Geometry
three-electrode setup as reported
Context
Cu-MOF/CF target electrode
Measurement source
6 · Electrochemical Characterizations · Figure 4A
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CV glucose concentration range0-6 mM glucoseText
Range
6 · Electrochemical Characterizations · Figure 4A

scan-rate-dependent cyclic voltammetry

Cu-MOF/CF electrode · Electrode

Cu-MOF/CF in 0.1 M NaOH with 1 mM glucose at scan rates from 20 to 200 mV s-1.

Temperature
room temperature
Geometry
three-electrode setup as reported
Context
Cu-MOF/CF target electrode
Measurement source
5 · Electrochemical Characterizations · Figure 3B,C
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
glucose oxidation control regimeoxidation peak currents directly proportional to square root of scan rate; diffusion-controlledText
Qualitative
5 · Electrochemical Characterizations · Figure 3C
scan-rate range20-200 mV s-1Text
Range
5 · Electrochemical Characterizations · Figure 3B
current density vs square-root scan-rate R2R2 = 0.9990Figure Axis
Rounded Reported
4 · Figure 3 · Figure 3C
current density vs square-root scan-rate slopey = 4.57x - 1.74Figure Axis
Rounded Reported
4 · Figure 3 · Figure 3C

pH-dependent glucose CV/current response

Cu-MOF/CF electrode · Electrode

Cu-MOF/CF response to 1 mM glucose in electrolytes from pH 10 to pH 14; 0.65 V and 50 mV s-1 noted in Figure 3D caption.

Temperature
room temperature
Geometry
three-electrode setup as reported
Context
Cu-MOF/CF target electrode
Measurement source
5 · Electrochemical Characterizations · Figure 3D
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
chosen optimal pHMarked as a best value within this paperpH 13Text
Exact Reported
5 · Electrochemical Characterizations · Figure 3D
pH range testedpH 10-14Text
Range
5 · Electrochemical Characterizations · Figure 3D