Synthesis · Cu-Based Conductive MOF Grown in situ on Cu Foam as a Highly Selective and Stable Non-Enzymatic Glucose Sensor

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

2 · Materials and Syntheses

Solventsacetone; ethanol; water

Atmospherenot reported

Temperatureroom temperature

Time0.75

Substrate orientationcopper foam control/substrate

Work-upSequential ultrasonication in acetone, ethanol and water for 15 min each.

Activationnone reported

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Solvent	acetone	15 min	2 · Materials and Syntheses
Solvent	ethanol	15 min	2 · Materials and Syntheses
Solvent	water	15 min	2 · Materials and Syntheses

Complete recipeSource: Main

2 · Materials and Syntheses · Scheme 1

Metal precursorsCu(CH3COO)2.H2O (0.08 mmol, 10 mg)

Linker precursorsHHTP (0.03 mmol, 7 mg)

SolventsH2O (4 mL); CF cleaning solvents: acetone, ethanol and water

Atmospherenot reported

Temperature85

Time12

Substrate orientationpretreated copper foam placed in a 20-mL glass bottle with the precursor solution

Work-upCopper foam was pre-cleaned by sequential ultrasonication in acetone, ethanol and water for 15 min; post-reaction washing/drying not reported.

Activationnone reported

Scalability contextFacile one-step hydrothermal method in a 20-mL glass bottle; no scale-up data reported.

Show 7 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	0.08 mmol, 10 mg	2 · Materials and Syntheses · Scheme 1
Linker	2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)	0.03 mmol, 7 mg	2 · Materials and Syntheses · Scheme 1
Solvent	H2O	4 mL	2 · Materials and Syntheses · Scheme 1
Other	copper foam (CF)	Not specified	2 · Materials and Syntheses · Scheme 1
Solvent	acetone	15 min ultrasonication cleaning step	2 · Materials and Syntheses · Scheme 1
Solvent	ethanol	15 min ultrasonication cleaning step	2 · Materials and Syntheses · Scheme 1
Solvent	water	15 min ultrasonication cleaning step	2 · Materials and Syntheses · Scheme 1

Partial recipeSource: Main

4 · Material Characterization · Figure 1C

Metal precursorsCu(CH3COO)2.H2O

Linker precursorsHHTP

SolventsH2O

Atmospherenot reported

Temperature85

Time12

Substrate orientationpowder collected from the reaction system; not a substrate-oriented film route

Work-upCollection/isolation method for the powder not described.

Activationnone reported

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	0.08 mmol, 10 mg in the reported Cu-MOF/CF recipe	4 · Material Characterization · Figure 1C
Linker	HHTP	0.03 mmol, 7 mg in the reported Cu-MOF/CF recipe	4 · Material Characterization · Figure 1C
Solvent	H2O	4 mL in the reported Cu-MOF/CF recipe	4 · Material Characterization · Figure 1C