cMOF Evidence Base
Electrical Transport — Organic Solvent Boosts Charge Storage and Charging Dynamics of Conductive MOF Supercapacitors

Measurement evidence

Electrical Transport

Organic Solvent Boosts Charge Storage and Charging Dynamics of Conductive MOF Supercapacitors · Chen M., Wu T., Niu L. et al. · Advanced Materials · 2024 · 2403202

2 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Mettler Toledo S230 SevenCompact conductivity meter

Electrical conductivity

bulk [Bmim][PF6]/ACN electrolyte ratio series · Unknown

Room-temperature conductivity of [Bmim][PF6]/ACN mixtures with different nIL:nsol ratios after sealed-vessel homogenisation.

Measurement source
9 · Experimental Section - Conductivity Measurements of Electrolytes · Figure S1; Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
bulk conductivity increase versus pure IL13.1 times——Text
Rounded Reported		2 · 2.1 Effects of Adding Solvent · Figure S1
peak bulk electrolyte conductivityMarked as a best value within this paper4.8 S m-1——Text
Rounded Reported		2 · 2.1 Effects of Adding Solvent · Figure S1
optimum IL-solvent rationIL:nsol = 0.107——Text
Exact Reported		2 · 2.1 Effects of Adding Solvent · Figure S1
bulk simulation ratio entry250 ion pairs; 5000 solvent molecules; nIL:nsol = 0.05——SI Table
Exact Reported		2 · Supplementary Note 1 · Table S1
bulk simulation ratio entry300 ion pairs; 1500 solvent molecules; nIL:nsol = 0.2——SI Table
Exact Reported		2 · Supplementary Note 1 · Table S1

MD-derived in-pore ionic conductivity

Electrical conductivityMolecular dynamics

MD model: Ni3(HITP)2 supercapacitor with [Bmim][PF6]/ACN · Model

In-pore conductivity for nIL:nsol = 0.05, 0.107 and 0.2 under a cell voltage of 2 V, extracted from charging curves/transmission-line analysis.

Measurement source
7 · Supplementary Note 2 · Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
in-pore ionic conductivity at nIL:nsol = 0.05visual estimate approx. 0.33 S m-1——Figure Axis
Approximate		7 · Supplementary Note 2 · Figure S7
in-pore ionic conductivity at nIL:nsol = 0.107Marked as a best value within this papervisual estimate approx. 0.51 S m-1——Figure Axis
Approximate		7 · Supplementary Note 2 · Figure S7
in-pore ionic conductivity at nIL:nsol = 0.2visual estimate approx. 0.26 S m-1——Figure Axis
Approximate		7 · Supplementary Note 2 · Figure S7