Measurement evidence
Conductive Metal-Organic Frameworks as Ion-to-Electron Transducers in Potentiometric Sensors · Mendecki L., Mirica K.A. · ACS Applied Materials and Interfaces · 2018 · 19248-19257
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
GCE/Ni3HHTP2 MOF/K+-ISM-II potentiometric device · Electrode
GCE/MOF/K+-ISM-II immersed in 1.0 x 10-3 M KCl with room lights switched on and off.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| K+-ISM-II photosensitivityMarked as a best value within this paper | <1 mV | — | < | Text Approximate | 6 · Potentiometric Ion Sensing · Figure S16 |
GCE/Ni3HHTP2 MOF/K+-ISM-I potentiometric device · Electrode
Valinomycin-based K+-ISM-I membrane on GCE/Ni3HHTP2 MOF.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| K+-ISM-I limit of detection, Ni3HHTP2 deviceMarked as a best value within this paper | 5.01 +/- 0.01 x 10-7 M | — | +/- 0.01 x 10-7 M | Text Exact Reported | 7 · Potentiometric Ion Sensing · Figure 5B |
| K+-ISM-I slope, Ni3HHTP2 deviceMarked as a best value within this paper | 58.2 +/- 1.0 mV decade-1 | — | +/- 1.0 mV/decade | Text Exact Reported | 7 · Potentiometric Ion Sensing · Figure 5B |
M3HHTP2 bulk powder series · Powder
K+-ISM-II devices using Ni3HHTP2, Co3HHTP2, or Cu3HHTP2 as underlying conductive layer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Co3HHTP2/K+-ISM-II analogue slopeMarked as a best value within this paper | 56.2 +/- 1.0 mV/decade | — | +/- 1.0 mV/decade | Caption Exact Reported | 14 · Potentiometric Responses · Figure S10 |
| Cu3HHTP2/K+-ISM-II analogue slope | 52.6 +/- 2.1 mV/decade | — | +/- 2.1 mV/decade | Caption Exact Reported | 14 · Potentiometric Responses · Figure S10 |
| Ni3HHTP2/K+-ISM-II analogue slope | 55.1 +/- 1.2 mV/decade | — | +/- 1.2 mV/decade | Caption Exact Reported | 14 · Potentiometric Responses · Figure S10 |
GCE/Ni3HHTP2 MOF/K+-ISM-II potentiometric device · Electrode
Stirred aqueous solution against double-junction Ag/AgCl reference at room temperature; at least three independent K+-ISEs.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| K+-ISM-II limit of detection, Ni3HHTP2 device | 6.76 +/- 0.03 x 10-6 M | — | +/- 0.03 x 10-6 M | Text Exact Reported | 6 · Potentiometric Ion Sensing · Figure 5B |
| K+-ISM-II slope, Ni3HHTP2 device | 54.1 +/- 1.0 mV decade-1 | — | +/- 1.0 mV/decade | Text Exact Reported | 6 · Potentiometric Ion Sensing · Figure 5B |
GCE/Ni3HHTP2 MOF/NO3--ISM potentiometric device · Electrode
Stirred aqueous solution against double-junction Ag/AgCl reference at room temperature; at least three independent NO3--ISEs.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NO3--ISM limit of detection | 6.31 +/- 0.01 x 10-7 M | — | +/- 0.01 x 10-7 M | Text Exact Reported | 6 · Potentiometric Ion Sensing · Figure 5A |
| NO3--ISM slope | 56.3 +/- 0.5 mV decade-1 | — | +/- 0.5 mV/decade | Text Exact Reported | 6 · Potentiometric Ion Sensing · Figure 5A |
GCE/Ni3HHTP2 MOF/K+-ISM-I potentiometric device · Electrode
K+-ISM-I electrode selectivity versus Ca2+, Na+, and NH4+ by unbiased separate solution method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| K+-ISM-I selectivity log KPOT versus Ca2+Marked as a best value within this paper | -5.46 +/- 0.09 | — | +/- 0.09 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S3 |
| K+-ISM-I selectivity log KPOT versus Na+ | -4.10 +/- 0.01 | — | +/- 0.01 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S3 |
| K+-ISM-I selectivity log KPOT versus NH4+ | -2.12 +/- 0.05 | — | +/- 0.05 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S3 |
GCE/Ni3HHTP2 MOF/K+-ISM-II potentiometric device · Electrode
K+-ISM-II electrode selectivity versus Ca2+, Na+, and NH4+ by unbiased separate solution method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| K+-ISM-II selectivity log KPOT versus Ca2+Marked as a best value within this paper | -3.28 +/- 0.02 | — | +/- 0.02 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S1 |
| K+-ISM-II selectivity log KPOT versus Na+ | -0.86 +/- 0.10 | — | +/- 0.10 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S1 |
| K+-ISM-II selectivity log KPOT versus NH4+ | -0.82 +/- 0.05 | — | +/- 0.05 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S1 |
GCE/Ni3HHTP2 MOF/NO3--ISM potentiometric device · Electrode
NO3--ISM electrode selectivity versus SO4(2-), Cl-, and Br-.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NO3--ISM selectivity log KPOT versus Br- | -0.48 +/- 0.05 | — | +/- 0.05 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S2 |
| NO3--ISM selectivity log KPOT versus Cl- | -1.82 +/- 0.01 | — | +/- 0.01 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S2 |
| NO3--ISM selectivity log KPOT versus SO4(2-)Marked as a best value within this paper | -3.15 +/- 0.01 | — | +/- 0.01 | SI Table Exact Reported | 16 · Selectivity Coefficients · Table S2 |
GCE/Ni3HHTP2 MOF/NO3--ISM potentiometric device · Electrode
NO3--ISM electrodes immersed in 1.0 x 10-3 M NH4NO3; long-term electrodes stored in ultra-pure water for 25 days.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NO3--ISM long-term standard-potential change | 15 mV change after 25 days | — | — | Text Rounded Reported | 6 · Potentiometric Ion Sensing · Figure S15 |
| NO3--ISM long-term standard-potential change, SI caption | ~10 mV +/- 3 after 25 days | — | +/- 3 mV | Caption Approximate | 17 · Long-term Stability · Figure S15 |
| NO3--ISM short-term potential driftMarked as a best value within this paper | 11.1 +/- 0.5 uA/h | — | +/- 0.5 uA/h | Text Exact Reported | 6 · Potentiometric Ion Sensing · Figure S14 |
GCE/Ni3HHTP2 MOF/K+-ISM-II potentiometric device · Electrode
Sequential immersion in 0.1 M KCl, 0.1 M NaCl, and 0.1 M KCl.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| K+-ISM-II water-layer drift | only very small potential drift during KCl/NaCl/KCl switching | — | — | Text Qualitative | 8 · Aqueous Layer Test · Figure 6B |
GCE/Ni3HHTP2 MOF/NO3--ISM potentiometric device · Electrode
Sequential immersion in 0.1 M NH4NO3, 0.1 M CaCl2, and 0.1 M NH4NO3.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NO3--ISM water-layer drift | very small potential drift after switching back to primary ion solution | — | — | Text Qualitative | 8 · Aqueous Layer Test · Figure 6A |