Shah J.H., Sharif S., Shahbaz M. et al. · Journal of Energy Storage · 2024 · 114058
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The Cu-PDA-MOF//AC hybrid device is claimed as a promising energy-storage material because it combines high specific capacity, energy density, power density and cycling stability.
Caveat: Performance is device-level and depends on the AC counter-electrode and electrode additives.
p007 · 5. Conclusions · Linked to 4 structured results
Although the abstract mentions surface area and porosity, no numerical BET surface area, pore volume, pore size or gas-sorption isotherm was found in the supplied text files or rendered pages.
Caveat: Could still be present in an unrendered image embedded in the office SI, but the supplied SI3 text only lists FTIR, TGA and simulated XRD figures.
p001 · Abstract
Cu-PDA-MOF acts as the battery-grade positive electrode and activated carbon as the capacitive-grade negative electrode in the hybrid device.
Caveat: Device assembly details such as separator and electrolyte are not fully specified in the extracted text.
p001 · Abstract · Linked to 3 structured results
FTIR shifts of carboxylate stretches relative to free PDA are interpreted as evidence that PDA binds copper through carboxylate oxygen atoms.
office text · FTIR & Thermal Analysis · Figs. S1-S2 · Linked to 5 structured results
The authors claim that the 1D Cu-PDA-MOF framework and pi-d conjugated pathways improve conductive behaviour and electrochemical performance.
Caveat: Conductivity is inferred from EIS and electrochemical behaviour; no direct electronic conductivity value in S/cm is reported.
p006 · 4.3 Discussion · Linked to 4 structured results
Charge storage is attributed to Cu+/Cu2+ redox involving OH- interaction with the Cu-PDA-MOF electrode.
Caveat: Mechanism is proposed from CV/GCD behaviour rather than operando oxidation-state measurement.
p004 · 4.1.1 Cyclic voltammetry · Eqs. 2-3 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu-PDA-MOF | C7 H7 Cu N O6Cu(II) centres coordinated by pyridine N, carboxylate O and aqua ligands · 2,6-pyridinedicarboxylic acid / pyridine-2,6-dicarboxylate (PDA/PDCA) | 1D · PristineMonoclinic P 21/c 1D coordination polymer; infinite 1D MOF growing along the 001 direction; described as having pi-d conjugated layers. | p002-p003 · Introduction; 3.2 Single-crystal structure of Cu-PDA-MOF · Figures 2 and 3 |
| Cu-PDA-MOF//AC hybrid supercapacitor device | Cu-PDA-MOF positive electrode paired with activated carbon negative electrodeCu centres in the Cu-PDA-MOF positive electrode · 2,6-pyridinedicarboxylate linker in Cu-PDA-MOF; activated carbon and PVDF are device components | unknown · CompositeAsymmetric hybrid supercapacitor / supercapattery assembled from battery-grade Cu-PDA-MOF and capacitive-grade activated carbon. | p005 · 4.2 Hybrid supercapacitor device performance · Figure 6 |
| 2,6-pyridinedicarboxylic acid control | not extractednone · 2,6-pyridinedicarboxylic acid | 0D · Model SystemFree ligand FTIR control. | office text · FTIR & Thermal Analysis · Fig. S2 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Activated-carbon negative electroderesearch_0844__mat__cu_pda_mof_ac_device | Electrode · Composite Component · Composite | Activated-carbon electrode prepared using the same proportions and mass balancing equation.nickel foam | p002-p003 · 2.3 Fabrication of electrodes · Eq. 1 |
| Cu-PDA-MOF//AC hybrid deviceresearch_0844__mat__cu_pda_mof_ac_device | Electrode · Composite Sample · Composite | Two-electrode supercapattery using Cu-PDA-MOF positive electrode and activated carbon negative electrode.two-electrode asymmetric device; nickel-foam-supported electrodes | p005 · 4.2 Hybrid supercapacitor device performance · Figure 6 |
| Cu-PDA-MOF blue crystalsresearch_0844__mat__cu_pda_mof | Single Crystal · Target Sample · Pristine Framework | As-synthesised blue crystals obtained from aqueous CuCl2.2H2O/PDA/NaOH solution after sonication and 10 days crystallisation. | p002 · 2.2 Synthesis of 1D Cu-PDA-MOF · Figure 1 |
| Cu-PDA-MOF working electrode on nickel foamresearch_0844__mat__cu_pda_mof | Electrode · Pristine Control · Composite | Drop-cast slurry of Cu-PDA-MOF, activated carbon and PVDF in NMP on conditioned nickel foam; dried at 70 deg C for 5 h.nickel foam, 1 cm2 x 1.5 cm2 | p002 · 2.3 Fabrication of electrodes |
| Free 2,6-PDA ligandresearch_0844__mat__pda_ligand_control | Powder · Model System · Model | Free ligand measured as FTIR comparison. | office text · FTIR & Thermal Analysis · Fig. S2 |