cMOF Evidence Base

Synthesis evidence

Electrochemical investigation of copper 1D conductive polymer for hybrid supercapacitor applications

Shah J.H., Sharif S., Shahbaz M. et al. · Journal of Energy Storage · 2024 · 114058

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Drop Cast

p002-p003 · 2.3 Fabrication of electrodes · Eq. 1

SolventsNMP; washing solvents 3 M HCl, acetone and CH3OH
Additivesactivated carbon; PVDF binder
Atmospherenot stated
Temperature70
Time5
Substrate orientationnickel foam
Work-upPrepared using the same proportions as the Cu-PDA-MOF electrode; AC mass balanced using Eq. (1).
Activationnot reported
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Additiveactivated carbonmass determined using Eq. (1)p002-p003 · 2.3 Fabrication of electrodes · Eq. 1
AdditivePVDF bindersame proportion as Cu-PDA-MOF electrodep002-p003 · 2.3 Fabrication of electrodes · Eq. 1
SolventNMPNot specifiedp002-p003 · 2.3 Fabrication of electrodes · Eq. 1
Vague recipeSource: Main

Route 2: Other

p005 · 4.2 Hybrid supercapacitor device performance · Figure 6

Metal precursorsCu-PDA-MOF positive electrode
Additivesactivated carbon negative electrode
Atmospherenot stated
Work-upAsymmetric two-electrode hybrid supercapacitor assembled with Cu-PDA-MOF positive electrode and activated carbon negative electrode.
Activationnot reported
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherCu-PDA-MOF positive electrodeNot specifiedp005 · 4.2 Hybrid supercapacitor device performance · Figure 6
Otheractivated carbon negative electrodeNot specifiedp005 · 4.2 Hybrid supercapacitor device performance · Figure 6
Partial recipeSource: Main

Route 3: Other

p002 · 2.2 Synthesis of 1D Cu-PDA-MOF · Figure 1

Metal precursorsCopper chloride dihydrate (26.9 mg, 0.2 mmol)
Linker precursors2,6-pyridinedicarboxylic acid (31.44 mg, 0.11 mmol)
Solventsdistilled water
AdditivesNaOH (8 mg, 0.2 mmol) to maintain pH 4
Atmospherenot stated; apparently ambient aqueous synthesis
Time240
Work-upSeparate aqueous solutions were sonicated 1 min, mixed, sonicated 15 min at 15 microns amplitude and 20 kHz; blue crystals appeared after ten days. Washing/drying/isolation details were not reported.
Activationnot reported
Scalability contextSmall-scale crystal synthesis; reported yield ca. 76%.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCopper chloride dihydrate26.9 mg, 0.2 mmolp002 · 2.2 Synthesis of 1D Cu-PDA-MOF · Figure 1
Linker2,6-pyridinedicarboxylic acid31.44 mg, 0.11 mmolp002 · 2.2 Synthesis of 1D Cu-PDA-MOF · Figure 1
Solventdistilled waterNot specifiedp002 · 2.2 Synthesis of 1D Cu-PDA-MOF · Figure 1
BaseNaOH8 mg, 0.2 mmol · pH 4 targetp002 · 2.2 Synthesis of 1D Cu-PDA-MOF · Figure 1
Partial recipeSource: Main

Route 4: Drop Cast

p002 · 2.3 Fabrication of electrodes

Metal precursorsCu-PDA-MOF active material
SolventsN-methylpyrollidone (NMP); washing solvents 3 M HCl, acetone and CH3OH
Additivesactivated carbon; PVDF binder
Atmospherenot stated
Temperature70
Time5
Substrate orientationnickel foam, 1 cm2 x 1.5 cm2
Work-upNickel foam washed with 3 M HCl, acetone and methanol; homogeneous slurry stirred about 6 h; active material drop-cast on nickel foam and dried for 5 h at 70 deg C.
Activationnot reported
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
OtherCu-PDA-MOF8 mgp002 · 2.3 Fabrication of electrodes
Additiveactivated carbon (AC)1 mgp002 · 2.3 Fabrication of electrodes
Additivepolyvinylidene fluoride (PVDF) binder1 mgp002 · 2.3 Fabrication of electrodes
SolventN-methylpyrollidone (NMP)70 uLp002 · 2.3 Fabrication of electrodes
Othernickel foam1 cm2 x 1.5 cm2p002 · 2.3 Fabrication of electrodes