Lu Y.-B., Liao Y.-Q., Dong L. et al. · Chemistry of Materials · 2021 · 7858-7868
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Compound 1 shows notable thermal and chemical stability: TGA stable to about 330 °C, PXRD retention after water/organic solvents, and pH 3-11 stability for 2 weeks.
Caveat: Stability is mainly phase-retention by PXRD and TGA; no post-treatment surface area or defect quantification reported.
p003 / 7860 · Thermal and Chemical Stabilities · Figures 2 and 3 · Linked to 4 structured results
Compound 1 acts as a selective aqueous fluorescence sensor for nitrobenzene with KSV = 680.52 M^-1 and a 2.89 x 10^-4 M detection limit.
Caveat: Application is solution fluorescence quenching; device-level sensor fabrication was not reported.
p008 / 7865 · Luminescence Sensing Properties · Figure 7 · Linked to 4 structured results
Compound 1 is a pristine 3D anionic Cu(I)-tetrazolate MOF, [Cu3(mtz)4]-, charge-balanced by Na+ cations and containing 1D channels.
Caveat: Main article Table 1 formula line appears to contain a typo; CIF formula is used for exact elemental formula.
p003 / 7860 · Structure Description and Discussion · Figure 1 · Linked to 3 structured results
Water vapour adsorption and uncoordinated tetrazolate N atoms in 1D channels enable water-assisted proton transport in compound 1.
Caveat: Hydrogen-bonding pathway is mechanistic interpretation rather than direct proton-position measurement.
p004-p006 / 7861-7863 · Proton Conduction · Figures 4 and 5c · Linked to 3 structured results
Nitrobenzene fluorescence quenching is attributed to charge transfer from tetrazole rings of mtz ligands to electron-deficient nitrobenzene adsorbed on the MOF surface.
Caveat: Mechanism is inferred from molecular orbital considerations and DOS assignments, not from direct time-resolved or adsorption spectroscopy.
p008 / 7865 · Luminescence Sensing Properties · Linked to 3 structured results
The authors assign proton conduction in compound 1 to a Grotthuss mechanism rather than Na+ ion migration or vehicle transport.
Caveat: Based primarily on activation energy threshold and structural plausibility; the figure label and text differ slightly for Ea.
p005 / 7862 · Proton Conduction · Figure 4d · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| compound 1; NaCu3(mtz)4; sodium copper(I) 5-methyltetrazolate MOF | NaCu3(mtz)4; CIF formula sum C8 H12 Cu3 N16 NaCu(I) centres in distorted tetrahedral CuN4 environments; Na+ counter-cations occupy one channel · mtz = 5-methyltetrazolate / C2H3N4-; two crystallographically independent mtz- ligands | 3D · Pristine3D anionic [Cu3(mtz)4]- framework with 1D channels; tetragonal I4(1)/acd by single-crystal XRD | p003 / 7860 · Results and Discussion - Structure Description and Discussion · Figure 1; Table 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| aqueous suspension of ground compound 1research_0854__mat__mof_1_nacu3_mtz4 | Powder · Target Sample · Pristine Framework | 2 mg ground 1 dispersed in 2 mL water and ultrasonicated for 0.5 h before fluorescence measurements | p007 / 7864 · Luminescence Sensing Properties · Figures 6 and 7 |
| crystal-structure model of compound 1research_0854__mat__mof_1_nacu3_mtz4 | Model · Model System · Model | experimental crystal structure used for DFT, band-structure, DOS and TOPOND bond-property calculations | p002 / 7859 · Experimental Section - Computation Procedures |
| compressed microcrystalline pellet of compound 1research_0854__mat__mof_1_nacu3_mtz4 | Pellet · Target Sample · Pristine Framework | microcrystalline sample compressed to 1.19 mm thickness and 2.5 mm diameter under 0.1 GPa; two sides connected to gold wires with gold paste1.19 mm | p002 / 7859 · Experimental Section - Materials and Instruments |
| yellow block single crystals of compound 1research_0854__mat__mof_1_nacu3_mtz4 | Single Crystal · Target Sample · Pristine Framework | as-synthesised single crystals filtered from mother liquor and dried in air | p002 / 7859 · Experimental Section - Synthesis of NaCu3(mtz)4 (1) |