Electrical Transport — Ultra-Stable Metal-Organic Framework with Concurrent High Proton Conductivity and Fluorescence Sensing for Nitrobenzene

4 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

compressed microcrystalline pellet of compound 1 · Pellet

100% RH; 30-70 °C conductivity data fitted to sigma*T = A exp(Ea/kBT)

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
activation energy for proton conduction	0.34 eV	—	—	Text Rounded Reported	p005 / 7862 · Proton Conduction · Figure 4d

compressed microcrystalline pellet of compound 1 · Pellet

30 °C; RH varied from 60% to 100%; compact pellet contacted with gold wires and gold paste

Temperature: 303
Atmosphere: controlled humid atmosphere, 60-100% RH
Geometry: 1.19 mm thick, 2.5 mm diameter compressed pellet; gold-wire contacts
Context: pristine MOF pellet under water-assisted conditions
Measurement source: SI p005-p006 · Table S2 · Table S2; Figure 4a,b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
proton conductivity at 30 °C and 100% RH	3.47 x 10^-3	—	—	SI Table Exact Reported	SI p006 · Table S2 · Table S2
proton conductivity at 30 °C and 60% RH	1.93 x 10^-7	—	—	SI Table Exact Reported	SI p006 · Table S2 · Table S2
proton conductivity at 30 °C and 70% RH	4.55 x 10^-6	—	—	SI Table Exact Reported	SI p006 · Table S2 · Table S2
proton conductivity at 30 °C and 80% RH	1.03 x 10^-4	—	—	SI Table Exact Reported	SI p006 · Table S2 · Table S2
proton conductivity at 30 °C and 90% RH	1.39 x 10^-3	—	—	SI Table Exact Reported	SI p006 · Table S2 · Table S2

compressed microcrystalline pellet of compound 1 · Pellet

100% RH; temperature varied from 30 to 70 °C; compact pellet contacted with gold wires and gold paste

Atmosphere: 100% RH
Geometry: 1.19 mm thick, 2.5 mm diameter compressed pellet; gold-wire contacts
Context: pristine MOF pellet under water-assisted conditions
Measurement source: SI p006 · Table S3 · Table S3; Figure 4c,d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
proton conductivity at 100% RH and 30 °C	3.47 x 10^-3	—	—	SI Table Exact Reported	SI p006 · Table S3 · Table S3
proton conductivity at 100% RH and 40 °C	4.99 x 10^-3	—	—	SI Table Exact Reported	SI p006 · Table S3 · Table S3
proton conductivity at 100% RH and 50 °C	6.54 x 10^-3	—	—	SI Table Exact Reported	SI p006 · Table S3 · Table S3
proton conductivity at 100% RH and 60 °C	9.24 x 10^-3	—	—	SI Table Exact Reported	SI p006 · Table S3 · Table S3
maximum reported proton conductivity at 100% RH and 70 °CMarked as a best value within this paper	1.33 x 10^-2	—	—	SI Table Exact Reported	SI p006 · Table S3 · Table S3

compressed microcrystalline pellet of compound 1 · Pellet

70 °C and 100% RH for 8 h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
conductivity stability over 8 h	No significant loss after 8 h at 70 °C and 100% RH	—	—	Text Qualitative	p005-p006 / 7862-7863 · Proton Conduction · Figure 5a