Complete recipeSource: Main
Route 1: Solvothermal
p002 / 7859 · Experimental Section - Synthesis of NaCu3(mtz)4 (1)
Metal precursorsCu(ClO4)2.6H2O (0.5 mmol)
Linker precursorsNaN3 (0.5 mmol) and acetonitrile; mtz ligand formed in situ by azide-nitrile cycloaddition
Solventsacetonitrile (8 mL); ethanol (2 mL)
AdditivesNaN3 also supplies Na+ counter-cation
Atmosphereautogenous pressure in sealed Teflon-lined stainless-steel container; no external gas specified
Temperature180
Time72
Work-upcooled to room temperature at 3.2 °C/h; yellow block crystals filtered off from solution and dried in air
Activationdried in air; no solvent-exchange or vacuum activation reported
Scalability contextSingle-crystal solvothermal recipe in 25 mL autoclave; 28% yield based on Cu; no scale-up demonstrated.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cu(ClO4)2.6H2O | 0.5 mmol | p002 / 7859 · Experimental Section - Synthesis of NaCu3(mtz)4 (1) |
| Linker | NaN3 | 0.5 mmol | p002 / 7859 · Experimental Section - Synthesis of NaCu3(mtz)4 (1) |
| Solvent | acetonitrile | 8 mL | p002 / 7859 · Experimental Section - Synthesis of NaCu3(mtz)4 (1) |
| Solvent | ethanol | 2 mL | p002 / 7859 · Experimental Section - Synthesis of NaCu3(mtz)4 (1) |