Diffraction Structure — Controlling the Spatiotemporal Self-Organization of Stimuli-Responsive Nanocrystals under Out-of-Equilibrium Conditions

Measurement evidence

Diffraction Structure

Controlling the Spatiotemporal Self-Organization of Stimuli-Responsive Nanocrystals under Out-of-Equilibrium Conditions · Damacet P., Shehayeb E.O., Mirica K.A. · Journal of the American Chemical Society · 2025 · 1584-1594

3 measurement groups · 1 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Powder X-ray diffraction (PXRD)

1D reaction-diffusion Ni3(HITP)2 Liesegang precipitation zones · Powder

Rigaku MiniFlex, Cu radiation, 3-40 degrees 2theta, 0.02 degree step, 4 degrees min-1 scan rate.

Atmosphere
ambient measurement not otherwise specified
Context
pristine RD-derived framework particles
Measurement source
2 · S1 Materials and methods · Figure S36
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource

PXRD

2D RD Ni3(HITP)2 interface particles · Powder

PXRD on particles from interface through Zone 3 of 2D reactor.

Context
pristine 2D RD-derived framework particles
Measurement source
1589 · 3.4 2D Liesegang Rings · Figure 4e
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource

PXRD after H2S exposure

2D RD Ni3(HITP)2 interface particles · Powder

PXRD before and after exposure to 80 ppm and 10000 ppm H2S; 10000 ppm exposure for 2 h also compared across zones and bulk.

Atmosphere
H2S
Geometry
drop-cast suspension on PXRD plate for interface sample
Context
pristine framework particles after analyte exposure
Measurement source
96 · S11.10 Structural stability · Figures S113-S115
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
PXRD structural stability after high-concentration H2S exposureno significant structural changes after 10000 ppm H2S for 2 hText
Qualitative
1591 · 3.5 Chemiresistive Detection · Figures S113-S115