cMOF Evidence Base
Diffraction Structure — Proton-Conductive 3D LnIII Metal–Organic Frameworks for Formic Acid Impedance Sensing

Measurement evidence

Diffraction Structure

Proton-Conductive 3D LnIII Metal–Organic Frameworks for Formic Acid Impedance Sensing · Liu R.-L., Qu W.-T., Dou B.-H. et al. · Chemistry - An Asian Journal · 2020 · 182-190

4 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

powder X-ray diffraction

X-ray diffraction and scattering

ZZU-1 crystalline sample · Single Crystal

PXRD after water, boiling water and pH treatment for ZZU-1 and ZZU-2

Atmosphere
aqueous water, HCl/NaOH pH solutions
Context
pristine framework
Measurement source
2 · Results and Discussion · Figure 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
PXRD acid/base stabilityPXRD maintained after acidic and alkali solutions up to 48 h——Text
Qualitative		3 · Results and Discussion · Figure 2
PXRD water/boiling-water stabilityPXRD patterns preserved after water one month or boiling water 24 h——Text
Qualitative		2 · Results and Discussion · Figure 2

hydrogen-bond parameter table

ZZU-1 crystalline sample · Single Crystal

Hydrogen bonding parameters for ZZU-1

Context
pristine framework
Measurement source
2 · Supporting Information · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZZU-1 hydrogen bond N2H2O9 angle170 deg——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond N2H2O9 D...A distance2.93 A——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O9H9AO10 angle165 deg——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O9H9AO10 D...A distance3.263 A——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O10H10AO9 angle176 deg——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O10H10AO9 D...A distance2.842 A——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O9H9BO2 angle164 deg——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O9H9BO2 D...A distance2.841 A——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O10H10BO8 angle175 deg——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O10H10BO8 D...A distance2.952 A——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O6H6AO10 angle171 deg——SI Table
Exact Reported		2 · Supporting Information · Table S1
ZZU-1 hydrogen bond O6H6AO10 D...A distance2.68 A——SI Table
Exact Reported		2 · Supporting Information · Table S1

single-crystal structure description from prior crystallographic work

ZZU-1 crystalline sample · Single Crystal

Structural features relevant to proton conduction described for ZZU-1

Context
pristine framework
Measurement source
2 · Results and Discussion · Figure 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZZU-1 framework dimensionality3D framework——Text
Qualitative		2 · Results and Discussion · Figure 1

isostructural assignment from prior crystallographic work

ZZU-2 crystalline sample · Single Crystal

ZZU-2 described as isomorphous/isostructural with ZZU-1

Context
pristine framework
Measurement source
2 · Results and Discussion · Figure 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZZU-2 isostructural assignmentisostructural/isomorphous with ZZU-1——Text
Qualitative		2 · Results and Discussion