cMOF Evidence Base

Synthesis evidence

Proton-Conductive 3D LnIII Metal–Organic Frameworks for Formic Acid Impedance Sensing

Liu R.-L., Qu W.-T., Dou B.-H. et al. · Chemistry - An Asian Journal · 2020 · 182-190

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Other

8 · Experimental Section - Stability experiment and activation

Metal precursorsas-synthesised ZZU-1
Linker precursorsretained framework linkers
Solventsnone reported
Additivesnone reported
Atmospherevacuum oven
Temperature65
Time18
Work-upevacuation under vacuum oven
Activation65 deg C under vacuum for 18 h
Scalability contextActivation scale not reported.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Otheras-synthesised ZZU-1 crystalsnot reported8 · Experimental Section - Stability experiment and activation
Vague recipeSource: Both

Route 2: Unknown

8 · Experimental Section - Reagents and Apparatus

Metal precursorsnot reported in supplied main/SI; cited literature method ref. 45
Linker precursorsnot reported in supplied main/SI; framework uses H3PhIDC and oxalate-derived ligands
Solventsnot reported
Additivesnot reported
Atmospherenot reported
Work-upnot reported
Activationnot reported for initial synthesis
Scalability contextNo scale or yield reported in the supplied documents.
Partial recipeSource: Main

Route 3: Other

8 · Experimental Section - Proton conductivity measurements

Metal precursorsground crystalline ZZU-1
Linker precursorsretained framework linkers
Solventsnone reported
Additivesnone reported
Atmosphereambient/not specified
Time0.0667
Work-upcompressed in abrasive tools into pellets at 3 MPa for 4 min
Activationequilibrated for 14 h under relative humidity before smooth impedance spectra
Scalability contextPellet dimensions were not reported.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Otherground crystalline ZZU-1not reported8 · Experimental Section - Proton conductivity measurements
Complete recipeSource: Main

Route 4: Other

8 · Experimental Section - Stability experiment and activation

Metal precursorsas-synthesised ZZU-2
Linker precursorsretained framework linkers
Solventsnone reported
Additivesnone reported
Atmospherevacuum oven
Temperature65
Time18
Work-upevacuation under vacuum oven
Activation65 deg C under vacuum for 18 h
Scalability contextActivation scale not reported.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Otheras-synthesised ZZU-2 crystalsnot reported8 · Experimental Section - Stability experiment and activation
Vague recipeSource: Both

Route 5: Unknown

8 · Experimental Section - Reagents and Apparatus

Metal precursorsnot reported in supplied main/SI; cited literature method ref. 46
Linker precursorsnot reported in supplied main/SI; framework uses H3PhIDC and oxalate-derived ligands
Solventsnot reported
Additivesnot reported
Atmospherenot reported
Work-upnot reported
Activationnot reported for initial synthesis
Scalability contextNo scale or yield reported in the supplied documents.
Partial recipeSource: Main

Route 6: Other

8 · Experimental Section - Proton conductivity measurements

Metal precursorsground crystalline ZZU-2
Linker precursorsretained framework linkers
Solventsnone reported
Additivesnone reported
Atmosphereambient/not specified
Time0.0667
Work-upcompressed in abrasive tools into pellets at 3 MPa for 4 min
Activationequilibrated for 14 h under relative humidity before smooth impedance spectra
Scalability contextPellet dimensions were not reported.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Otherground crystalline ZZU-2not reported8 · Experimental Section - Proton conductivity measurements