Porosity — Proton Conductive Metal-Organic Framework Encapsulating Emissive Hexacyanidochromate(III) Ions for Ratiometric and Lifetime-Based Detection of Humidity and Temperature

3 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

dehydrated 1deh bulk powder · Powder

Methanol sorption/desorption isotherm for dehydrated 1deh at 25 C followed by water sorption for same sample.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1deh methanol sorption reversibility	methanol sorption found irreversible; adsorbed methanol remains at pMeOH/p0 = 0	—	—	Text Qualitative	p.5 · 2.2 Dynamic Vapor Sorption · Figure S12
1deh methanol uptake at high p/p0	approximately 4 MeOH per Cr unit at pMeOH/p0 about 0.9	—	—	Figure Axis Approximate	S26 · Figure S12 · Figure S12

air-stable 1a bulk polycrystalline powder · Powder

Water vapour sorption/desorption isotherm at 25 C; p/p0/RH varied 0-0.9.

Temperature: 298
Atmosphere: N2 carrier atmosphere; water vapour
Context: primary proton-conductive MOF
Measurement source: p.5 · 2.2 Dynamic Vapor Sorption and Proton Conductivity Studies · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1a water sorption reversibility	sorption and desorption isotherms coincide; reversible process	—	—	Text Qualitative	p.5 · 2.2 Dynamic Vapor Sorption · Figure 3a
1a water uptake at p/p0 = 0.9Marked as a best value within this paper	ca. 8 H2O molecules per CrIII unit at p/p0 0.9	—	—	Text Approximate	p.5 · 2.2 Dynamic Vapor Sorption · Figure 3a
1a water uptake at first sorption step	approximately 5 H2O molecules per CrIII unit	—	—	Text Approximate	p.5 · 2.2 Dynamic Vapor Sorption · Figure 3a

air-dried 2a bulk powder · Powder

Water vapour sorption/desorption isotherm for 2a at 25 C.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2a water uptake at p/p0 = 0.9	maximal number of water molecules of 9 per one CoIII unit at p/p0 0.9	—	—	Text Approximate	p.5 · 2.2 Dynamic Vapor Sorption · Figure S11