Complete recipeSource: Both
Route 1: Other
S3 · Synthesis of 1 and preparation of its air-dried form, 1a
Metal precursorsSrII(NO3)2 (0.05 mmol, 10.6 mg); (bmba)3[CrIII(CN)6] (0.05 mmol, 44.2 mg)
Linker precursors4,4'-bpdo (0.05 mmol, 18.8 mg)
Solvents0.25 mL H2O + 1 mL MeOH for Sr/linker; 2 mL MeOH for Cr precursor; methanol and diethyl ether washes
Additivesbis(alpha-methylbenzyl)amine cation present in precursor salt; no template reported in final framework
Atmosphereclosed vial stored in dark; drying in air under ambient laboratory conditions
Temperature21
Timenot specified for crystallisation; longer standing under ambient conditions for mass stabilisation
Work-upcrystals collected by suction filtration, washed with small portions of methanol and diethyl ether, left to dry in air
Activationambient air drying to 1a; no thermal activation for 1a
Scalability contextYield 16.4 mg (10.4%) based on SrII(NO3)2 for 1a.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | SrII(NO3)2 | 0.05 mmol (10.6 mg) | S3 · Synthesis of 1 and preparation of its air-dried form, 1a |
| Linker | 4,4'-bpdo | 0.05 mmol (18.8 mg) | S3 · Synthesis of 1 and preparation of its air-dried form, 1a |
| Other | (bmba)3[CrIII(CN)6] | 0.05 mmol (44.2 mg) | S3 · Synthesis of 1 and preparation of its air-dried form, 1a |
| Solvent | H2O | 0.25 mL | S3 · Synthesis of 1 and preparation of its air-dried form, 1a |
| Solvent | methanol | 1 mL + 2 mL | S3 · Synthesis of 1 and preparation of its air-dried form, 1a |
| Solvent | diethyl ether wash | small portions | S3 · Synthesis of 1 and preparation of its air-dried form, 1a |